A supermolecular building block approach for construction of chiral metal-organic frameworks

A supermolecular building block approach for construction of chiral metal-organic frameworks

A supermolecular building block approach was utilized to fabricate three isoreticular chiral metal-organic frameworks with different pore environments based on enantiopure tetracarboxylate ligands of biphenol, which were found to be highly effective heterogeneous catalysts for the CO 2 fixation reac...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-07, Vol.55 (59), p.8639-8642
Hauptverfasser: Jiang, Hong, Chen, Kai-Jie, Zheng, Fan-Fan, Chen, Xu, Liu, Yan, Cui, Yong
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Crystal structure
Crystallography
Crystals
Metal-organic frameworks
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Zusammenfassung:A supermolecular building block approach was utilized to fabricate three isoreticular chiral metal-organic frameworks with different pore environments based on enantiopure tetracarboxylate ligands of biphenol, which were found to be highly effective heterogeneous catalysts for the CO 2 fixation reaction. Three isoreticular chiral porous metal-organic frameworks (MOFs) with different pore environments are synthesized through a supermolecular building block approach.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc02787d