Design of NiO Flakes@CoMoO 4 Nanosheets Core-Shell Architecture on Ni Foam for High-Performance Supercapacitors

As typical electrode materials for supercapacitors, low specific capacitance and insufficient cycling stability of transition metal oxides (TMOs) are still the problems that need to be solved. Design of core-shell structure is considered as an effective method for preparation of high-performance ele...

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Veröffentlicht in:Nanoscale research letters 2019-07, Vol.14 (1), p.221
Hauptverfasser: Zhou, Enmin, Tian, Liangliang, Cheng, Zhengfu, Fu, Chunping
Format: Artikel
Sprache:eng
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Zusammenfassung:As typical electrode materials for supercapacitors, low specific capacitance and insufficient cycling stability of transition metal oxides (TMOs) are still the problems that need to be solved. Design of core-shell structure is considered as an effective method for preparation of high-performance electrode materials. In this work, NiO flakes@CoMoO nanosheets/Ni foam (NiO flakes@CoMoO NSs/NF) core-shell architecture was constructed by a two-step hydrothermal method. Interestingly, the CoMoO NSs are vertically grown on the surface of NiO flakes, forming a two-dimensional (2D) branched core-shell structure. The porous core-shell architecture has relatively high surface area, effective ions channels, and abundant redox sites, resulting in excellent electrochemical performance. As a positive electrode for supercapacitors, NiO flakes@CoMoO NSs/NF core-shell architecture exhibits excellent capacitive performance in terms of high specific capacitance (1097 F/g at 1 A/g) and outstanding cycling stability (97.5% after 2000 circles). The assembled asymmetric supercapacitor (ASC) of NiO flakes@CoMoO NSs/NF//active carbon (AC)/NF possesses a maximum energy density of 25.8 Wh/kg at power density of 894.7 W/kg. The results demonstrate that NiO flakes@CoMoO NSs/NF electrode displays potential applications in supercapacitors and the design of 2D branched core-shell architecture paves an ideal way to obtain high-performance TMOs electrodes.
ISSN:1931-7573
DOI:10.1186/s11671-019-3054-3