A decanuclear [DyZn] cluster: a {Zn} rectangle surrounding an octahedral {Dy} single molecule magnet
An octahedral {Dy III 6 } cage within a diamagnetic {Zn II 4 } rectangle is reported, with magnetic relaxation studies revealing single-molecule magnet behaviour for the complex under zero external dc field with U eff = 43 K and τ o = 1 × 10 −5 s. The synthesis, structure and magnetic relaxation pro...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019-03, Vol.48 (11), p.3566-357 |
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| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | An octahedral {Dy
III
6
} cage within a diamagnetic {Zn
II
4
} rectangle is reported, with magnetic relaxation studies revealing single-molecule magnet behaviour for the complex under zero external dc field with
U
eff
= 43 K and
τ
o
= 1 × 10
−5
s.
The synthesis, structure and magnetic relaxation properties of a decanuclear [Dy
III
6
Zn
II
4
] complex are reported. |
|---|---|
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/c9dt00440h |