Increasing the activity of copper exchanged mordenite in the direct isothermal conversion of methane to methanol by Pt and Pd doping

PtCu- and PdCu-mordenite allow for isothermal reaction at 200 °C for the stepwise methane to methanol conversion with comparably high yields. In contrast to traditional Cu-zeolites, these materials are more reactive under isothermal conditions than after high temperature activation. PtCu- and PdCu-m...

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Veröffentlicht in:Chemical science (Cambridge) 2019, Vol.1 (1), p.167-171
Hauptverfasser: Tomkins, P, Mansouri, A, Sushkevich, V, van der Wal, L. I, Bozbag, S. E, Krumeich, F, Ranocchiari, M, van Bokhoven, J. A
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Sprache:eng
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Zusammenfassung:PtCu- and PdCu-mordenite allow for isothermal reaction at 200 °C for the stepwise methane to methanol conversion with comparably high yields. In contrast to traditional Cu-zeolites, these materials are more reactive under isothermal conditions than after high temperature activation. PtCu- and PdCu-mordenite allow for isothermal reaction at 200 °C for the stepwise methane to methanol conversion with higher yields under isothermal conditions than after high temperature activation.
ISSN:2041-6520
2041-6539
DOI:10.1039/c8sc02795a