A clickable NHC-Au()-complex for the preparation of stimulus-responsive metallopeptide amphiphiles
We report the synthesis of an alkyne functionalised NHC-Au( i )-complex which is conjugated with amphiphilic oligopeptides using a copper( i ) catalysed cycloaddition. The resulting Au( i )-metalloamphiphiles are shown to self-assemble into charge-regulated stimulus-responsive supramolecular polymer...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018, Vol.54 (68), p.9498-951 |
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| container_issue | 68 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 54 |
| creator | Lewe, V Preuss, M Wo nica, E. A Spitzer, D Otter, R Besenius, P |
| description | We report the synthesis of an alkyne functionalised NHC-Au(
i
)-complex which is conjugated with amphiphilic oligopeptides using a copper(
i
) catalysed cycloaddition. The resulting Au(
i
)-metalloamphiphiles are shown to self-assemble into charge-regulated stimulus-responsive supramolecular polymers in water
via
a weakly cooperative polymerisation mechanism.
We report the synthesis of an alkyne functionalised NHC-Au(
i
)-complex which is conjugated with amphiphilic oligopeptides using a copper(
i
) catalysed cycloaddition. |
| doi_str_mv | 10.1039/c8cc05622f |
| format | Article |
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i
)-complex which is conjugated with amphiphilic oligopeptides using a copper(
i
) catalysed cycloaddition. The resulting Au(
i
)-metalloamphiphiles are shown to self-assemble into charge-regulated stimulus-responsive supramolecular polymers in water
via
a weakly cooperative polymerisation mechanism.
We report the synthesis of an alkyne functionalised NHC-Au(
i
)-complex which is conjugated with amphiphilic oligopeptides using a copper(
i
) catalysed cycloaddition.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c8cc05622f</identifier><identifier>PMID: 30090888</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Alkynes ; Cycloaddition ; Supramolecular polymers</subject><ispartof>Chemical communications (Cambridge, England), 2018, Vol.54 (68), p.9498-951</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-7aaf96fcb6802f7713197635c85716ce35ad2e6df00cbb189356ef00fc163be03</citedby><cites>FETCH-LOGICAL-c337t-7aaf96fcb6802f7713197635c85716ce35ad2e6df00cbb189356ef00fc163be03</cites><orcidid>0000-0001-7478-4459</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4009,27902,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30090888$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lewe, V</creatorcontrib><creatorcontrib>Preuss, M</creatorcontrib><creatorcontrib>Wo nica, E. A</creatorcontrib><creatorcontrib>Spitzer, D</creatorcontrib><creatorcontrib>Otter, R</creatorcontrib><creatorcontrib>Besenius, P</creatorcontrib><title>A clickable NHC-Au()-complex for the preparation of stimulus-responsive metallopeptide amphiphiles</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>We report the synthesis of an alkyne functionalised NHC-Au(
i
)-complex which is conjugated with amphiphilic oligopeptides using a copper(
i
) catalysed cycloaddition. The resulting Au(
i
)-metalloamphiphiles are shown to self-assemble into charge-regulated stimulus-responsive supramolecular polymers in water
via
a weakly cooperative polymerisation mechanism.
We report the synthesis of an alkyne functionalised NHC-Au(
i
)-complex which is conjugated with amphiphilic oligopeptides using a copper(
i
) catalysed cycloaddition.</description><subject>Alkynes</subject><subject>Cycloaddition</subject><subject>Supramolecular polymers</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpd0c9LBCEUB3CJoh9bl-6F0GULpnRcHee4DNUGUZeCboPjPmnKWU1nov773LY2SB6o-OHx-IrQISXnlLDyQkutCRd5bjbQLmVikvGJfNpcnnmZFWzCd9BejC8kLcrlNtphhJRESrmLminWttWvqrGA72ZVNh3Gp5l2nbfwgY0LuH8G7AN4FVTfugV2Bse-7QY7xCxA9G4R23fAHfTKWufB9-0csOr8c5vKQtxHW0bZCAc_-wg9Xl0-VLPs9v76ppreZpqxos8KpUwpjG6EJLkpCspoWQjGteQFFRoYV_McxNwQopuGypJxAeliNBWsAcJGaLzq64N7GyD2dddGDdaqBbgh1jmRIhekkCLRk3_0xQ1hkaZLqkyhTgSnSZ2tlA4uxgCm9qHtVPisKamXydeVrKrv5K8SPv5pOTQdzNf0N-oEjlYgRL1-_fs69gVhqofG</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Lewe, V</creator><creator>Preuss, M</creator><creator>Wo nica, E. A</creator><creator>Spitzer, D</creator><creator>Otter, R</creator><creator>Besenius, P</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-7478-4459</orcidid></search><sort><creationdate>2018</creationdate><title>A clickable NHC-Au()-complex for the preparation of stimulus-responsive metallopeptide amphiphiles</title><author>Lewe, V ; Preuss, M ; Wo nica, E. A ; Spitzer, D ; Otter, R ; Besenius, P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-7aaf96fcb6802f7713197635c85716ce35ad2e6df00cbb189356ef00fc163be03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Alkynes</topic><topic>Cycloaddition</topic><topic>Supramolecular polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lewe, V</creatorcontrib><creatorcontrib>Preuss, M</creatorcontrib><creatorcontrib>Wo nica, E. A</creatorcontrib><creatorcontrib>Spitzer, D</creatorcontrib><creatorcontrib>Otter, R</creatorcontrib><creatorcontrib>Besenius, P</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lewe, V</au><au>Preuss, M</au><au>Wo nica, E. A</au><au>Spitzer, D</au><au>Otter, R</au><au>Besenius, P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A clickable NHC-Au()-complex for the preparation of stimulus-responsive metallopeptide amphiphiles</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2018</date><risdate>2018</risdate><volume>54</volume><issue>68</issue><spage>9498</spage><epage>951</epage><pages>9498-951</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We report the synthesis of an alkyne functionalised NHC-Au(
i
)-complex which is conjugated with amphiphilic oligopeptides using a copper(
i
) catalysed cycloaddition. The resulting Au(
i
)-metalloamphiphiles are shown to self-assemble into charge-regulated stimulus-responsive supramolecular polymers in water
via
a weakly cooperative polymerisation mechanism.
We report the synthesis of an alkyne functionalised NHC-Au(
i
)-complex which is conjugated with amphiphilic oligopeptides using a copper(
i
) catalysed cycloaddition.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30090888</pmid><doi>10.1039/c8cc05622f</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-7478-4459</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2018, Vol.54 (68), p.9498-951 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_pubmed_primary_30090888 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alkynes Cycloaddition Supramolecular polymers |
| title | A clickable NHC-Au()-complex for the preparation of stimulus-responsive metallopeptide amphiphiles |
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