Solution Plasma-assisted Bimetallic Oxide Alloy Nanoparticles of Pt and Pd Embedded within Two-dimensional Ti3C2Tx Nanosheets as Highly Active Electrocatalysts for Overall Water-splitting

Exploiting high-efficiency and low-cost bifunctional electrocatalysts for hydrogen evolution (HER) and oxygen evolution reactions (OER) has been actively encouraged because of their potential applications in the field of clean energy. In this paper, we reported a novel electrocatalyst based on an exfoliated two-dimensional (2D) MXene (Ti3C2Tx) loaded with bimetallic oxide alloy nanoparticles (NPs) of Pt and Pd (represented by PtOaPdObNPs@Ti3C2Tx), which was synthesized via solution plasma (SP) modification. The prepared materials were then utilized as highly efficient bifunctional electrocatalysts toward HER and OER in alkaline solution. At a high plasma input power (200 W), bimetallic oxide alloy nanoparticles of Pt and Pd or nanoclusters with different metallic valence states deposited onto the Ti3C2Tx nanosheets. Due to the synergism of the noble metal NPs and the Ti3C2Tx nanosheets, the electrocatalytic results revealed that the as-prepared PtOaPdObNPs@Ti3C2Tx nanosheets under the plasma input power of 200 W for 3 min catalyst only required a low overpotential to attain 10 mA cm-2 for HER (57 mV) in 0.5 M H2SO4 solution and OER (1.63 V) in 0.1 M KOH sollution. Moreover, water electrolysis using this catalyst achieved a water splitting current density of 10 mA cm-2 at a low cell voltage of 1.53 V in 1.0 M KOH solution. These results suggested that the hybridization of the ultra-extremely low usage of PtOa/PdOb NPs (1.07 μg cm-2) and Ti3C2Tx nanosheets by SP will expand the applications of other clean energy reactions to achieve sustainable energy.