Molecular Paneling by Coordination: An M 15 L 6 Hexahedral Molecular Capsule having Clefts for Reversible Guest Inclusion
Only one positional isomer is obtained from the assembly of 21 small components. A triangular molecular panel with five coordination sites is assembled upon complexation with [Pd (en)] (en=ethylenediamine) into a unique M L hexahedral coordination capsule (see X-ray structure). The capsule can encap...
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Veröffentlicht in: | Angewandte Chemie International Edition 2001-07, Vol.40 (14), p.2620 |
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creator | Umemoto, Kazuhiko Tsukui, Hitoshi Kusukawa, Takahiro Biradha, Kumar Fujita, Makoto |
description | Only one positional isomer is obtained from the assembly of 21 small components. A triangular molecular panel with five coordination sites is assembled upon complexation with [Pd
(en)] (en=ethylenediamine) into a unique M
L
hexahedral coordination capsule (see X-ray structure). The capsule can encapsulate/exchange organic guests reversibly through the clefts at the nonbinding sites of the capsule. |
format | Article |
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L
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title | Molecular Paneling by Coordination: An M 15 L 6 Hexahedral Molecular Capsule having Clefts for Reversible Guest Inclusion |
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