Molecular Paneling by Coordination: An M 15 L 6 Hexahedral Molecular Capsule having Clefts for Reversible Guest Inclusion

Molecular Paneling by Coordination: An M 15 L 6 Hexahedral Molecular Capsule having Clefts for Reversible Guest Inclusion

Only one positional isomer is obtained from the assembly of 21 small components. A triangular molecular panel with five coordination sites is assembled upon complexation with [Pd (en)] (en=ethylenediamine) into a unique M L hexahedral coordination capsule (see X-ray structure). The capsule can encap...

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Veröffentlicht in:Angewandte Chemie International Edition 2001-07, Vol.40 (14), p.2620
Hauptverfasser: Umemoto, Kazuhiko, Tsukui, Hitoshi, Kusukawa, Takahiro, Biradha, Kumar, Fujita, Makoto
Format: Artikel
Sprache:eng
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Zusammenfassung:Only one positional isomer is obtained from the assembly of 21 small components. A triangular molecular panel with five coordination sites is assembled upon complexation with [Pd (en)] (en=ethylenediamine) into a unique M L hexahedral coordination capsule (see X-ray structure). The capsule can encapsulate/exchange organic guests reversibly through the clefts at the nonbinding sites of the capsule.
ISSN:1521-3773