Ce 16 Si 15 O 6 N 32 -An Oxonitridosilicate with Silicon Octahedrally Coordinated by Nitrogen
A rarity in solid-state chemistry is octahedrally coordinated silicon. Ce Si O N is the first nitridosilicate with this structural motif. Most oxosilicates containing octahedrally coordinated silicon are high-pressure phases. In contrast to that Ce Si O N has been synthesized under ambient pressure....
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| Veröffentlicht in: | Angewandte Chemie International Edition 1999-02, Vol.38 (3), p.357 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A rarity in solid-state chemistry is octahedrally coordinated silicon. Ce
Si
O
N
is the first nitridosilicate with this structural motif. Most oxosilicates containing octahedrally coordinated silicon are high-pressure phases. In contrast to that Ce
Si
O
N
has been synthesized under ambient pressure. An SiN
octahedron that is surrounded by two parallel rings formed from six Si(O,N)
tetrahedra is depicted. |
|---|---|
| ISSN: | 1521-3773 |