Ti 2 Nb 6 Cl 14 O 4 : A Unique 2D-1D Network Combination in Niobium Cluster Chemistry

Ti 2 Nb 6 Cl 14 O 4 : A Unique 2D-1D Network Combination in Niobium Cluster Chemistry

Layers of niobium clusters that are linked to each other through zigzag chains of edge-sharing [TiCl O ] ocatahedra are the central structural features of the title compound. Bridging of the chains by [(Nb Cl O )Cl ] clusters results in the formation of empty tunnels (a section of the structure is s...

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Veröffentlicht in:Angewandte Chemie International Edition 1998-03, Vol.37 (4), p.522
Hauptverfasser: Anokhina, Ekaterina V, Essig, Michael W, Lachgar, Abdessadek
Format: Artikel
Sprache:eng
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Zusammenfassung:Layers of niobium clusters that are linked to each other through zigzag chains of edge-sharing [TiCl O ] ocatahedra are the central structural features of the title compound. Bridging of the chains by [(Nb Cl O )Cl ] clusters results in the formation of empty tunnels (a section of the structure is shown on the right).
ISSN:1521-3773
DOI:10.1002/(SICI)1521-3773(19980302)37:4<522::AID-ANIE522>3.0.CO;2-Y