Chemistry of C 84 : Separation of Three Constitutional Isomers and Optical Resolution of D 2 -C 84 by Using the "Bingel-Retro-Bingel" Strategy

Chemistry of C 84 : Separation of Three Constitutional Isomers and Optical Resolution of D 2 -C 84 by Using the "Bingel-Retro-Bingel" Strategy

The pure enantiomers of D -C as well as a third constitutional isomer of this higher fullerene were produced by a retro-Bingel reaction on the first organic derivatives of C (see scheme). These derivatives were synthesized by Bingel cyclopropenation of C , separated, and unambiguously structurally c...

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Veröffentlicht in:Angewandte Chemie International Edition 1999-06, Vol.38 (11), p.1613
Hauptverfasser: Crassous, Jeanne, Rivera, José, Fender, Nicolette S, Shu, Lianhe, Echegoyen, Luis, Thilgen, Carlo, Herrmann, Andreas, Diederich, François
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Sprache:eng
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Zusammenfassung:The pure enantiomers of D -C as well as a third constitutional isomer of this higher fullerene were produced by a retro-Bingel reaction on the first organic derivatives of C (see scheme). These derivatives were synthesized by Bingel cyclopropenation of C , separated, and unambiguously structurally characterized.
ISSN:1521-3773
DOI:10.1002/(SICI)1521-3773(19990601)38:11<1613::AID-ANIE1613>3.0.CO;2-M