An Electrochemical Sensor of Poly(EDOT-pyridine-EDOT)/Graphitic Carbon Nitride Composite for Simultaneous Detection of Cd 2+ and Pb 2

In this study, poly(2,5-bis(3,4-ethylenedioxythienyl)pyridine)/graphitic carbon nitride composites (poly(BPE)/g-C₃N₄) were prepared by an in situ chemical polymerization method. Composites were characterized by using Fourier transform infrared spectroscopy (FT-IR), ultraviolet⁻visible absorption spectra (UV⁻vis), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Furthermore, electrochemical sensors were applied for the electrochemical determination of Cd and Pb using the differential pulse voltammetry (DPV) method. The results indicated that 10 wt % poly(BPE)/g-C₃N₄ composite-modified electrode exhibited linear detection ranging from 0.12 to 7.2 μM and 0.08 to 7.2 μM for Cd and Pb , with detection limits (S/N = 3) of 0.018 μM and 0.00324 μM. Interference analysis suggested that the 10 wt % poly(BPE)/g-C₃N₄-modified electrode can be applied for the detection of the Cd and Pb in real samples.