Photochemically deoxygenating solvents for triplet-triplet annihilation photon upconversion operating in air

Sulfoxides and cyclic ureas are photochemically deoxygenating solvents in which the oxidative stress could be released and efficient triplet-triplet annihilation photon upconversion (TTA-UC) can operate in air. Such solvents can be practically screened out by harnessing the property of photo-activat...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (31), p.397-391
Hauptverfasser: Wan, Shigang, Lin, Jinxiong, Su, Huimin, Dai, Junfeng, Lu, Wei
Format: Artikel
Sprache:eng
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Zusammenfassung:Sulfoxides and cyclic ureas are photochemically deoxygenating solvents in which the oxidative stress could be released and efficient triplet-triplet annihilation photon upconversion (TTA-UC) can operate in air. Such solvents can be practically screened out by harnessing the property of photo-activated phosphorescence. The solvent is the solution: sulfoxides and cyclic ureas are self-deoxygenating solvents in which efficient TTA-UC can operate in air, as predicted by photo-activated phosphorescence.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc00780b