Quick high-temperature hydrothermal synthesis of mesoporous materials with 3D cubic structure for the adsorption of lysozyme
Three-dimensional cage-like mesoporous FDU-12 materials with large tuneable pore sizes ranging from 9.9 to 15.6 nm were prepared by varying the synthesis temperature from 100 to 200 °C for the aging time of just 2 h using a tri-block copolymer F-127(EO 106 PO 70 EO 106 ) as the surfactant and 1,3,5-...
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creator | Lawrence, Geoffrey Baskar, Arun V El-Newehy, Mohammed H Cha, Wang Soo Al-Deyab, Salem S Vinu, Ajayan |
description | Three-dimensional cage-like mesoporous FDU-12 materials with large tuneable pore sizes ranging from 9.9 to 15.6 nm were prepared by varying the synthesis temperature from 100 to 200 °C for the aging time of just 2 h using a tri-block copolymer F-127(EO
106
PO
70
EO
106
) as the surfactant and 1,3,5-trimethyl benzene as the swelling agent in an acidic condition. The mesoporous structure and textural features of FDU-12-HX (where H denotes the hydrothermal method and X denotes the synthesis temperature) samples were elucidated and probed using x-ray diffraction, N
2
adsorption,
29
Si magic angle spinning nuclear magnetic resonance, scanning electron microscopy and transmission electron microscopy. It has been demonstrated that the aging time can be significantly reduced from 72 to 2 h without affecting the structural order of the FDU-12 materials with a simple adjustment of the synthesis temperature from 100 to 200 °C. Among the materials prepared, the samples prepared at 200 °C had the highest pore volume and the largest pore diameter. Lysozyme adsorption experiments were conducted over FDU-12 samples prepared at different temperatures in order to understand their biomolecule adsorption capacity, where the FDU-12-HX samples displayed high adsorption performance of 29 μmol g
−1
in spite of shortening the actual synthesis time from 72 to 2 h. Further, the influence of surface area, pore volume and pore diameter on the adsorption capacity of FDU-12-HX samples has been investigated and results are discussed in correlation with the textural parameters of the FDU-12-HX and other mesoporous adsorbents including SBA-15, MCM-41, KIT-5, KIT-6 and CMK-3. |
doi_str_mv | 10.1088/1468-6996/16/2/024806 |
format | Article |
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106
PO
70
EO
106
) as the surfactant and 1,3,5-trimethyl benzene as the swelling agent in an acidic condition. The mesoporous structure and textural features of FDU-12-HX (where H denotes the hydrothermal method and X denotes the synthesis temperature) samples were elucidated and probed using x-ray diffraction, N
2
adsorption,
29
Si magic angle spinning nuclear magnetic resonance, scanning electron microscopy and transmission electron microscopy. It has been demonstrated that the aging time can be significantly reduced from 72 to 2 h without affecting the structural order of the FDU-12 materials with a simple adjustment of the synthesis temperature from 100 to 200 °C. Among the materials prepared, the samples prepared at 200 °C had the highest pore volume and the largest pore diameter. Lysozyme adsorption experiments were conducted over FDU-12 samples prepared at different temperatures in order to understand their biomolecule adsorption capacity, where the FDU-12-HX samples displayed high adsorption performance of 29 μmol g
−1
in spite of shortening the actual synthesis time from 72 to 2 h. Further, the influence of surface area, pore volume and pore diameter on the adsorption capacity of FDU-12-HX samples has been investigated and results are discussed in correlation with the textural parameters of the FDU-12-HX and other mesoporous adsorbents including SBA-15, MCM-41, KIT-5, KIT-6 and CMK-3.</description><identifier>ISSN: 1468-6996</identifier><identifier>EISSN: 1878-5514</identifier><identifier>DOI: 10.1088/1468-6996/16/2/024806</identifier><identifier>PMID: 27877767</identifier><identifier>CODEN: STAMCV</identifier><language>eng</language><publisher>United States: Taylor & Francis</publisher><subject>Adsorption ; Benzene ; Biomolecules ; Block copolymers ; Diameters ; Electron microscopy ; Focus on Future Leaders in Nanoarchitectonics ; High temperature ; Lysozyme ; mesoporous ; Microscopy ; nanoporous ; NMR ; Nuclear magnetic resonance ; Porosity ; Spinning ; Spinning (materials) ; Surface chemistry ; Synthesis ; Three dimensional</subject><ispartof>Science and technology of advanced materials, 2015-04, Vol.16 (2), p.024806-24816</ispartof><rights>2015 National Institute for Materials Science 2015</rights><rights>2015 National Institute for Materials Science</rights><rights>2015 National Institute for Materials Science. This work is licensed under the Creative Commons Attribution License http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c707t-886d14000ed4ac055e61401ef8bf3253a5d9083f1d5b1d736af705efe49b7dd23</citedby><cites>FETCH-LOGICAL-c707t-886d14000ed4ac055e61401ef8bf3253a5d9083f1d5b1d736af705efe49b7dd23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1088/1468-6996/16/2/024806/pdf$$EPDF$$P50$$Giop$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5036462/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,2102,27502,27924,27925,38868,38890,53791,53793,53840,53867,59143,59144</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27877767$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lawrence, Geoffrey</creatorcontrib><creatorcontrib>Baskar, Arun V</creatorcontrib><creatorcontrib>El-Newehy, Mohammed H</creatorcontrib><creatorcontrib>Cha, Wang Soo</creatorcontrib><creatorcontrib>Al-Deyab, Salem S</creatorcontrib><creatorcontrib>Vinu, Ajayan</creatorcontrib><title>Quick high-temperature hydrothermal synthesis of mesoporous materials with 3D cubic structure for the adsorption of lysozyme</title><title>Science and technology of advanced materials</title><addtitle>STAM</addtitle><addtitle>Sci. Technol. Adv. Mater</addtitle><description>Three-dimensional cage-like mesoporous FDU-12 materials with large tuneable pore sizes ranging from 9.9 to 15.6 nm were prepared by varying the synthesis temperature from 100 to 200 °C for the aging time of just 2 h using a tri-block copolymer F-127(EO
106
PO
70
EO
106
) as the surfactant and 1,3,5-trimethyl benzene as the swelling agent in an acidic condition. The mesoporous structure and textural features of FDU-12-HX (where H denotes the hydrothermal method and X denotes the synthesis temperature) samples were elucidated and probed using x-ray diffraction, N
2
adsorption,
29
Si magic angle spinning nuclear magnetic resonance, scanning electron microscopy and transmission electron microscopy. It has been demonstrated that the aging time can be significantly reduced from 72 to 2 h without affecting the structural order of the FDU-12 materials with a simple adjustment of the synthesis temperature from 100 to 200 °C. Among the materials prepared, the samples prepared at 200 °C had the highest pore volume and the largest pore diameter. Lysozyme adsorption experiments were conducted over FDU-12 samples prepared at different temperatures in order to understand their biomolecule adsorption capacity, where the FDU-12-HX samples displayed high adsorption performance of 29 μmol g
−1
in spite of shortening the actual synthesis time from 72 to 2 h. Further, the influence of surface area, pore volume and pore diameter on the adsorption capacity of FDU-12-HX samples has been investigated and results are discussed in correlation with the textural parameters of the FDU-12-HX and other mesoporous adsorbents including SBA-15, MCM-41, KIT-5, KIT-6 and CMK-3.</description><subject>Adsorption</subject><subject>Benzene</subject><subject>Biomolecules</subject><subject>Block copolymers</subject><subject>Diameters</subject><subject>Electron microscopy</subject><subject>Focus on Future Leaders in Nanoarchitectonics</subject><subject>High temperature</subject><subject>Lysozyme</subject><subject>mesoporous</subject><subject>Microscopy</subject><subject>nanoporous</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Porosity</subject><subject>Spinning</subject><subject>Spinning (materials)</subject><subject>Surface chemistry</subject><subject>Synthesis</subject><subject>Three dimensional</subject><issn>1468-6996</issn><issn>1878-5514</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>0YH</sourceid><sourceid>O3W</sourceid><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><sourceid>DOA</sourceid><recordid>eNqNkklv1DAAhSMEoqXwE0CWuHAJY8frXBBV2SpVQkhwthwvE5ckDrZDFcSPx9OZbggBJ9vxe59f7FdVTxF8iaAQK0SYqNl6zVaIrZoVbIiA7F51iAQXNaWI3C_zK81B9SilcwghQw15WB00XHDOGT-sfn6avf4KOr_p6myHyUaV52hBt5gYcmfjoHqQlrFMk08gODDYFKYQw5zAoLKNXvUJXPjcAfwG6Ln1GqQcZ32JcSGCYgXKpBCn7MO4RfRLCj-WwT6uHrjitk_241H15d3bzycf6rOP709Pjs9qzSHPtRDMIFLSW0OUhpRaVpbIOtE63FCsqFlDgR0ytEWGY6Ych9Q6S9YtN6bBR9XpjmuCOpdT9IOKiwzKy8sPIW6kitnr3kqNneJIYUyFI1bZlmlOnTGarxuHW1hYr3asaW4Ha7Qdc1T9HejdndF3chO-SwoxI2wb5sUeEMO32aYsB5-07Xs12nKpEgmC14iU9_wPaUMJLVlRkT7_TXoe5jiWW5UNxg1kDeGsqOhOpWNIKVp3nRtBua2V3FZGbisjEZON3NWq-J7d_ulr11WPbpL6MN2cnLIabnPkZFyRoj9I_3X-671nLI0a1EWIvZFZLX2ILqpR-yTx3xG_ACCr_Hk</recordid><startdate>20150401</startdate><enddate>20150401</enddate><creator>Lawrence, Geoffrey</creator><creator>Baskar, Arun V</creator><creator>El-Newehy, Mohammed H</creator><creator>Cha, Wang Soo</creator><creator>Al-Deyab, Salem S</creator><creator>Vinu, Ajayan</creator><general>Taylor & Francis</general><general>IOP Publishing</general><general>Taylor & Francis Ltd</general><general>Taylor & Francis Group</general><scope>0YH</scope><scope>O3W</scope><scope>TSCCA</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7U5</scope><scope>7XB</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>JG9</scope><scope>L7M</scope><scope>M2O</scope><scope>MBDVC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope><scope>7SR</scope><scope>7X8</scope><scope>5PM</scope><scope>DOA</scope></search><sort><creationdate>20150401</creationdate><title>Quick high-temperature hydrothermal synthesis of mesoporous materials with 3D cubic structure for the adsorption of lysozyme</title><author>Lawrence, Geoffrey ; Baskar, Arun V ; El-Newehy, Mohammed H ; Cha, Wang Soo ; Al-Deyab, Salem S ; Vinu, Ajayan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c707t-886d14000ed4ac055e61401ef8bf3253a5d9083f1d5b1d736af705efe49b7dd23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Adsorption</topic><topic>Benzene</topic><topic>Biomolecules</topic><topic>Block copolymers</topic><topic>Diameters</topic><topic>Electron microscopy</topic><topic>Focus on Future Leaders in Nanoarchitectonics</topic><topic>High temperature</topic><topic>Lysozyme</topic><topic>mesoporous</topic><topic>Microscopy</topic><topic>nanoporous</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Porosity</topic><topic>Spinning</topic><topic>Spinning (materials)</topic><topic>Surface chemistry</topic><topic>Synthesis</topic><topic>Three dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lawrence, Geoffrey</creatorcontrib><creatorcontrib>Baskar, Arun V</creatorcontrib><creatorcontrib>El-Newehy, Mohammed H</creatorcontrib><creatorcontrib>Cha, Wang Soo</creatorcontrib><creatorcontrib>Al-Deyab, Salem S</creatorcontrib><creatorcontrib>Vinu, Ajayan</creatorcontrib><collection>Access via Taylor & Francis (Open Access Collection)</collection><collection>Institute of Physics Open Access Journal Titles</collection><collection>IOPscience (Open Access)</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Research Library</collection><collection>Research Library (Corporate)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><collection>Engineered Materials Abstracts</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Science and technology of advanced materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lawrence, Geoffrey</au><au>Baskar, Arun V</au><au>El-Newehy, Mohammed H</au><au>Cha, Wang Soo</au><au>Al-Deyab, Salem S</au><au>Vinu, Ajayan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quick high-temperature hydrothermal synthesis of mesoporous materials with 3D cubic structure for the adsorption of lysozyme</atitle><jtitle>Science and technology of advanced materials</jtitle><stitle>STAM</stitle><addtitle>Sci. Technol. Adv. Mater</addtitle><date>2015-04-01</date><risdate>2015</risdate><volume>16</volume><issue>2</issue><spage>024806</spage><epage>24816</epage><pages>024806-24816</pages><issn>1468-6996</issn><eissn>1878-5514</eissn><coden>STAMCV</coden><abstract>Three-dimensional cage-like mesoporous FDU-12 materials with large tuneable pore sizes ranging from 9.9 to 15.6 nm were prepared by varying the synthesis temperature from 100 to 200 °C for the aging time of just 2 h using a tri-block copolymer F-127(EO
106
PO
70
EO
106
) as the surfactant and 1,3,5-trimethyl benzene as the swelling agent in an acidic condition. The mesoporous structure and textural features of FDU-12-HX (where H denotes the hydrothermal method and X denotes the synthesis temperature) samples were elucidated and probed using x-ray diffraction, N
2
adsorption,
29
Si magic angle spinning nuclear magnetic resonance, scanning electron microscopy and transmission electron microscopy. It has been demonstrated that the aging time can be significantly reduced from 72 to 2 h without affecting the structural order of the FDU-12 materials with a simple adjustment of the synthesis temperature from 100 to 200 °C. Among the materials prepared, the samples prepared at 200 °C had the highest pore volume and the largest pore diameter. Lysozyme adsorption experiments were conducted over FDU-12 samples prepared at different temperatures in order to understand their biomolecule adsorption capacity, where the FDU-12-HX samples displayed high adsorption performance of 29 μmol g
−1
in spite of shortening the actual synthesis time from 72 to 2 h. Further, the influence of surface area, pore volume and pore diameter on the adsorption capacity of FDU-12-HX samples has been investigated and results are discussed in correlation with the textural parameters of the FDU-12-HX and other mesoporous adsorbents including SBA-15, MCM-41, KIT-5, KIT-6 and CMK-3.</abstract><cop>United States</cop><pub>Taylor & Francis</pub><pmid>27877767</pmid><doi>10.1088/1468-6996/16/2/024806</doi><tpages>11</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Adsorption Benzene Biomolecules Block copolymers Diameters Electron microscopy Focus on Future Leaders in Nanoarchitectonics High temperature Lysozyme mesoporous Microscopy nanoporous NMR Nuclear magnetic resonance Porosity Spinning Spinning (materials) Surface chemistry Synthesis Three dimensional |
title | Quick high-temperature hydrothermal synthesis of mesoporous materials with 3D cubic structure for the adsorption of lysozyme |
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