Manauealide C and anhydrodebromoaplysiatoxin, toxic constituents of the Hawaiian red alga, Gracilaria coronopifolia

Manauealide C and anhydrodebromoaplysiatoxin, toxic constituents of the Hawaiian red alga, Gracilaria coronopifolia

Manauealide C (1) and anhydrodebromoaplysiatoxin (4), toxic constituent of the Hawaiian red alga, Gracilaria coronopifolia which has been concerned with food poisoning cases, were studied. The absolute structure of manauealide c was determined as 1 by chemical conversion and spectroscopic methods. T...

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Veröffentlicht in:Bioscience, biotechnology, and biochemistry biotechnology, and biochemistry, 1998, Vol.62 (5), p.1011-1013
Hauptverfasser: Nagai, H. (Suntory Inst. for Bioorganic Research, Shimamoto, Osaka (Japan)), Kan, Y, Fujita, T, Sakamoto, B, Hokama, Y
Format: Artikel
Sprache:eng
Schlagworte:
absolute configuration
anhydrodebromoaplysiatoxin
Biological and medical sciences
CHEMICAL STRUCTURE
ENVENENAMIENTO
ESPECTROMETRIA
ESTRUCTURA QUIMICA
GRACILARIA
Gracilaria coronopifolia
HAWAI
HAWAII
INTOXICATION
manauealide C
Marine
marine algal toxin
Medical sciences
Plant poisons toxicology
POISONING
SPECTROMETRIE
SPECTROMETRY
STRUCTURE CHIMIQUE
SUBSTANCE TOXIQUE
SUSTANCIAS TOXICAS
TOXIC SUBSTANCES
TOXICIDAD
TOXICITE
TOXICITY
Toxicology
TOXINAS
TOXINE
TOXINS
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Zusammenfassung:Manauealide C (1) and anhydrodebromoaplysiatoxin (4), toxic constituent of the Hawaiian red alga, Gracilaria coronopifolia which has been concerned with food poisoning cases, were studied. The absolute structure of manauealide c was determined as 1 by chemical conversion and spectroscopic methods. The first complete assignment of 13C chemical shifts for anhydrodebromoaplysiatoxin (4) was established. The biological activity of 4 was also investigated
ISSN:0916-8451
1347-6947
DOI:10.1271/bbb.62.1011