Size-matched recognition of large anions by cyanostar macrocycles is saved when solvent-bias is avoided

Size-matched recognition of large anions by cyanostar macrocycles is saved when solvent-bias is avoided

The size-dependent recognition of large anions by shape-persistent macrocycles is poorly understood. To address this shortcoming, we created a bulky cyanostar that only forms 1 : 1 complexes and show the affinities best follow the expectations of size matching but only when solvent bias is removed....

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (56), p.8683-8686
Hauptverfasser: Qiao, Bo, Anderson, Joseph. R, Pink, Maren, Flood, Amar H
Format: Artikel
Sprache:eng
Schlagworte:
Affinity
Anions
Bias
Macrocyclic compounds
Matching
Recognition
Solvents
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Beschreibung
Zusammenfassung:The size-dependent recognition of large anions by shape-persistent macrocycles is poorly understood. To address this shortcoming, we created a bulky cyanostar that only forms 1 : 1 complexes and show the affinities best follow the expectations of size matching but only when solvent bias is removed. A bulky cyanostar that only forms 1 : 1 complexes was created to study the poorly understood size dependent recognition of large anions by shape-persistent macrocycles.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc03463b