Triggering autocatalytic reaction by host-guest interactions

The acceleration of a sequential reaction through electrostatic alteration of substrate basicity within a supramolecular host is demonstrated. In the presence of the host, the reaction, which is autocatalytic, starts much sooner and exhibits substrate size selectivity. The acceleration of a sequenti...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (22), p.4191-4194
Hauptverfasser:	Sashuk, Volodymyr, Butkiewicz, Helena, Fia kowski, Marcin, Danylyuk, Oksana
Format:	Artikel
Sprache:	eng
Schlagworte:	Acceleration Alterations Basicity Electrostatics Selectivity
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The acceleration of a sequential reaction through electrostatic alteration of substrate basicity within a supramolecular host is demonstrated. In the presence of the host, the reaction, which is autocatalytic, starts much sooner and exhibits substrate size selectivity. The acceleration of a sequential reaction through electrostatic alteration of substrate basicity within a supramolecular host is demonstrated.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c5cc10063a