Exceptionally strong and robust millimeter-scale graphene-alumina composite membranes

Graphene has attracted attention as a potential strengthening material and functional component in suspended membranes as utilized in micro and nanosystems. Development of a practical and scalable fabrication process is a necessary step to allow the exceptional material properties of graphene to be...

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Veröffentlicht in:Nanotechnology 2014-09, Vol.25 (35), p.355701-7
Hauptverfasser: Berdova, Maria, Perros, Alexander Pyymaki, Kim, Wonjae, Riikonen, Juha, Ylitalo, Tuomo, Heino, Jouni, Li, Changfeng, Kassamakov, Ivan, Hæggström, Edward, Lipsanen, Harri, Franssila, Sami
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Sprache:eng
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Zusammenfassung:Graphene has attracted attention as a potential strengthening material and functional component in suspended membranes as utilized in micro and nanosystems. Development of a practical and scalable fabrication process is a necessary step to allow the exceptional material properties of graphene to be fully exploited in composite structures. Using standard and scalable microfabrication processes, we fabricated free-standing chemical vapor deposition monolayer graphene-reinforced Al2O3 composite membranes, 0.5 mm in diameter, that are strong and robust. Bulge tests revealed that the graphene reinforcement increased the membrane fracture strength by a factor of at least three and maximum sustainable strain from 0.28% to at least 0.69%. We show that the graphene-reinforced membranes are even tolerant to significant cracking without loss of membrane integrity. The graphene composite membranes' freestanding area of ∼200 000 m2 is almost a thousand times larger than suspended graphene membranes reported elsewhere. The presented graphene composite membranes may be seen as representing an interesting new class of durable composite materials warranting further study and having potential for broad applicability in a variety of fields.
ISSN:0957-4484
1361-6528
DOI:10.1088/0957-4484/25/35/355701