Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1'-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

Fe2(CO)4(μ-dppf)(μ-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2014-12, Vol.50 (8), p.945
Hauptverfasser:	Ghosh, Shishir, Hogarth, Graeme, Hollingsworth, Nathan, Holt, Katherine B, Kabir, Shariff E, Sanchez, Ben E
Format:	Artikel
Sprache:	eng
Schlagworte:	Biocompatible Materials - chemistry Biocompatible Materials - metabolism Catalysis Coordination Complexes - chemistry Coordination Complexes - metabolism Crystallography, X-Ray Electrons Ferrous Compounds - chemistry Hydrogen - chemistry Hydrogen - metabolism Hydrogenase - chemistry Hydrogenase - metabolism Molecular Conformation Oxidation-Reduction Phosphines - chemistry Protons
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Beschreibung
Zusammenfassung:	Fe2(CO)4(μ-dppf)(μ-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.
ISSN:	1364-548X
DOI:	10.1039/c3cc46456c