Half-sandwich arene ruthenium complexes: synthetic strategies and relevance in catalysis

Half-sandwich arene ruthenium complexes exhibit versatile chemistry, serve as excellent precursors and find potential applications in many organic transformations. This review mainly focuses on the chemistry of piano-stool ruthenium complexes with special emphasis on the achiral or chiral-at-ruthenium center. Also, it deals with the synthesis, nomenclature and stereochemistry of arene ruthenium complexes along with mechanistic insights into the epimerization reactions and their applications in catalytic organic transformations with some selected examples. The syntheses, nomenclature and stereochemistry of half-sandwich arene ruthenium complexes with mechanistic insights into epimerization and catalytic applications have been presented.