A triangulo palladium cluster consisting of μ3-capping silyl ligands

We report on the utility of multifunctional, κ(1)Si:κ(3)S-coordinated tris(methimazolyl)silanide ligands [Si(mt(Me))(3)](-) for the stabilisation of a triangulo palladium cluster [Pd(3){Si(mt(Me))(3)}(2)] (3) consisting of very unusual μ(3)-capping SiR(3) donors. Differences to the corresponding pla...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (1), p.221
Hauptverfasser:	Armbruster, Felix, Meyer, Jens, Baldes, Alexander, Burgos, Pascual Oña, Fernández, Ignacio, Breher, Frank
Format:	Artikel
Sprache:	eng
Schlagworte:	Computer Simulation Crystallography, X-Ray Ligands Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Palladium - chemistry Silanes - chemistry Thermodynamics
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Zusammenfassung:	We report on the utility of multifunctional, κ(1)Si:κ(3)S-coordinated tris(methimazolyl)silanide ligands [Si(mt(Me))(3)](-) for the stabilisation of a triangulo palladium cluster [Pd(3){Si(mt(Me))(3)}(2)] (3) consisting of very unusual μ(3)-capping SiR(3) donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.
ISSN:	1364-548X
DOI:	10.1039/c002435j