"Determination of the absolute configuration of (+)-2,7(14),10-bisabolatrien-1-ol-4-one from Japanese cedar, Cryptomeria japonica."

"Determination of the absolute configuration of (+)-2,7(14),10-bisabolatrien-1-ol-4-one from Japanese cedar, Cryptomeria japonica."

"The absolute configuration of (+)-2,7(14),10-bisabolatrien-1-o1-4-one, a peculiar sesquiterpenol in the Japanese cedar, Cryptomeria japonica, was determined as (1S,6R)-2,7(14),10-bisabolatrien-1-o1-4-one by comparing the specific rotation values of cryptomeriones respectively converted from (+...

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Veröffentlicht in:Bioscience, biotechnology, and biochemistry biotechnology, and biochemistry, 2002-09, Vol.66 (9), p.1997-2000
Hauptverfasser: "Kim, C.S. (Kochi Univ., Nankoku (Japan). Faculty of Agriculture), Morisawa, J, Nishiyama, N, Kashiwagi, T, Tebayashi, S, Horiike, M.
Format: Artikel
Sprache:eng
Schlagworte:
(+)-2,7,10-bisabolatrien-1-ol-4-one
(1S,6R)-2,7,10-bisabolatrien-1-ol-4-one
Biological and medical sciences
BIOSYNTHESIS
CARVONE
Chemical constitution
CHEMICAL STRUCTURE
Cryptomeria - chemistry
CRYPTOMERIA JAPONICA
cryptomerione
Fundamental and applied biological sciences. Psychology
Molecular Structure
Optical Rotation
Plant physiology and development
Sesquiterpenes - chemistry
SESQUITERPENOIDS
TERPENOIDS
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Beschreibung
Zusammenfassung:"The absolute configuration of (+)-2,7(14),10-bisabolatrien-1-o1-4-one, a peculiar sesquiterpenol in the Japanese cedar, Cryptomeria japonica, was determined as (1S,6R)-2,7(14),10-bisabolatrien-1-o1-4-one by comparing the specific rotation values of cryptomeriones respectively converted from (+)-2,7(14),10-bisabolatrien-1-o1-4-one and synthesized from (R)-(-)-carvone. "
ISSN:0916-8451
1347-6947
DOI:10.1271/bbb.66.1997