Efficient Copper(II)-Catalyzed Transamidation of Non-Activated Primary Carboxamides and Ureas with Amines

Efficient Copper(II)-Catalyzed Transamidation of Non-Activated Primary Carboxamides and Ureas with Amines

Amid(e) them all: Primary carboxamides and ureas react with aromatic and aliphatic amines in the presence of a copper catalyst to give a wide range of functionalized amides (see scheme).

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Veröffentlicht in:Angewandte Chemie International Edition 2012-04, Vol.51 (16), p.3905-3909
Hauptverfasser: Zhang , Min, Imm, Sebastian, Bähn, Sebastian, Neubert, Lorenz, Neumann, Helfried, Beller, Matthias
Format: Artikel
Sprache:eng
Schlagworte:
Aliphatic amines
Amides
Amides - chemistry
Amination
Amines
Amines - chemistry
Catalysis
Catalysts
Copper
Copper - chemistry
homogeneous catalysis
Stereoisomerism
transamidation
Urea - chemistry
Ureas
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Beschreibung
Zusammenfassung:Amid(e) them all: Primary carboxamides and ureas react with aromatic and aliphatic amines in the presence of a copper catalyst to give a wide range of functionalized amides (see scheme).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201108599