Cupric Superoxo-Mediated Intermolecular C−H Activation Chemistry
The new cupric superoxo complex [LCuII(O2 •−)]+, which possesses particularly strong O−O and Cu−O bonding, is capable of intermolecular C−H activation of the NADH analogue 1-benzyl-1,4-dihydronicotinamide (BNAH). Kinetic studies indicated a first-order dependence on both the Cu complex and BNAH with...
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| Veröffentlicht in: | Journal of the American Chemical Society 2011-02, Vol.133 (6), p.1702-1705 |
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| container_end_page | 1705 |
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| container_issue | 6 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 133 |
| creator | Peterson, Ryan L. Himes, Richard A. Kotani, Hiroaki Suenobu, Tomoyoshi Tian, Li Siegler, Maxime A. Solomon, Edward I. Fukuzumi, Shunichi Karlin, Kenneth D. |
| description | The new cupric superoxo complex [LCuII(O2 •−)]+, which possesses particularly strong O−O and Cu−O bonding, is capable of intermolecular C−H activation of the NADH analogue 1-benzyl-1,4-dihydronicotinamide (BNAH). Kinetic studies indicated a first-order dependence on both the Cu complex and BNAH with a deuterium kinetic isotope effect (KIE) of 12.1, similar to that observed for certain copper monooxygenases. |
| doi_str_mv | 10.1021/ja110466q |
| format | Article |
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| ispartof | Journal of the American Chemical Society, 2011-02, Vol.133 (6), p.1702-1705 |
| issn | 0002-7863 1520-5126 |
| language | eng |
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| source | MEDLINE; ACS Journals |
| subjects | Carbon - chemistry Copper - chemistry Hydrogen - chemistry Kinetics Models, Molecular Molecular Conformation Organometallic Compounds - chemistry Oxidation-Reduction |
| title | Cupric Superoxo-Mediated Intermolecular C−H Activation Chemistry |
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