A promising new route towards single-molecule magnets based on the oxalate ligand

A unique purely lanthanide-based single-molecule magnet (SMM) with an oxalate bridge has been designed through a rational synthetic approach. This strategy opens up new opportunities to design SMMs through the premeditated choice of a blocking ligand and suitable oxalate bridge.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (9), p.1506-1508
Hauptverfasser: Xu, Gong-Feng, Wang, Qing-Lun, Gamez, Patrick, Ma, Yue, Clérac, Rodolphe, Tang, Jinkui, Yan, Shi-Ping, Cheng, Peng, Liao, Dai-Zheng
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Sprache:eng
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Zusammenfassung:A unique purely lanthanide-based single-molecule magnet (SMM) with an oxalate bridge has been designed through a rational synthetic approach. This strategy opens up new opportunities to design SMMs through the premeditated choice of a blocking ligand and suitable oxalate bridge.
ISSN:1359-7345
1364-548X
DOI:10.1039/b920215c