A novel organic–inorganic hybrid turbine-shaped hexa-Zn sandwiched tungstoarsenate(iii)

A novel organic–inorganic hybrid turbine-shaped hexa-Zn sandwiched tungstoarsenate(iii)

Hexa-Zn-tungstoarsenate(iii) [Zn(Hen)]6[B-[small alpha]-AsW9O33]2[middle dot]6H2O (1) consists of two [B-[small alpha]-AsW9O33]9- subunits incorporating a unique turbine-shaped [Zn(Hen)]618+ cluster, which represents the first hexa-ZnII substituted sandwich-type polyoxometalate.

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Veröffentlicht in:CrystEngComm 2011-01, Vol.13 (15), p.4834-4837
Hauptverfasser: Niu, Jing-Yang, Ma, Xiang, Zhao, Jun-Wei, Ma, Peng-Tao, Zhang, Chao, Wang, Jing-Ping
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
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Zusammenfassung:Hexa-Zn-tungstoarsenate(iii) [Zn(Hen)]6[B-[small alpha]-AsW9O33]2[middle dot]6H2O (1) consists of two [B-[small alpha]-AsW9O33]9- subunits incorporating a unique turbine-shaped [Zn(Hen)]618+ cluster, which represents the first hexa-ZnII substituted sandwich-type polyoxometalate.
ISSN:1466-8033
1466-8033
DOI:10.1039/c1ce05358b