Correlating Pt-P bond lengths and Pt-P coupling constants

Correlating Pt-P bond lengths and Pt-P coupling constants

The X-ray structures of () cis-PtBr(2)(P(OMe)(3))(2), () cis-PtBr(2)(P(OMe)(2)Ph)(2), () cis-PtBr(2)(P(OMe)Ph(2))(2), () cis-PtBr(2)(PPh(3))(2), () cis-PtI(2)(P(OMe)(3))(2), () cis-PtI(2)(P(OMe)(2)Ph)(2), () cis-PtI(2)(P(OMe)Ph(2))(2) and () cis-PtI(2)(PPh(3))(2) are reported and compared with the p...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (37), p.8620-8625
Hauptverfasser: Waddell, Paul G, Slawin, Alexandra M Z, Woollins, J Derek
Format: Artikel
Sprache:eng
Schlagworte:
Bonding
Chlorides
Constants
Coordination Complexes - chemistry
Correlation
Crystallography, X-Ray
Joining
Molecular Conformation
Phosphorus - chemistry
Platinum
Platinum - chemistry
Prints
X-rays
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Zusammenfassung:The X-ray structures of () cis-PtBr(2)(P(OMe)(3))(2), () cis-PtBr(2)(P(OMe)(2)Ph)(2), () cis-PtBr(2)(P(OMe)Ph(2))(2), () cis-PtBr(2)(PPh(3))(2), () cis-PtI(2)(P(OMe)(3))(2), () cis-PtI(2)(P(OMe)(2)Ph)(2), () cis-PtI(2)(P(OMe)Ph(2))(2) and () cis-PtI(2)(PPh(3))(2) are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt-P} varies linearly with the Pt-P bond length (l(Pt-P) = 2.421 -J/24255) for these 12 complexes.
ISSN:1477-9226
1477-9234
DOI:10.1039/c003256e