A facile catalyst-free synthesis of gem-dihydroperoxides with aqueous hydrogen peroxide

A facile catalyst-free synthesis of gem-dihydroperoxides with aqueous hydrogen peroxide

gem-Dihydroperoxides were easily obtained from the corresponding carbonyl compounds in high yields through a catalyst-free method with aqueous H(2)O(2) (35%) in 1,2-dimethoxyethane at room temperature.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (10), p.1772-1774
Hauptverfasser: Tada, Norihiro, Cui, Lei, Okubo, Hiroaki, Miura, Tsuyoshi, Itoh, Akichika
Format: Artikel
Sprache:eng
Schlagworte:
Carbonyl compounds
Catalysis
Catalysts
Hydrogen peroxide
Hydrogen Peroxide - chemistry
Magnetic Resonance Spectroscopy
Synthesis
Temperature
Water - chemistry
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Beschreibung
Zusammenfassung:gem-Dihydroperoxides were easily obtained from the corresponding carbonyl compounds in high yields through a catalyst-free method with aqueous H(2)O(2) (35%) in 1,2-dimethoxyethane at room temperature.
ISSN:1359-7345
1364-548X
DOI:10.1039/b917056a