Chiral porphyrin dimer with a macrocyclic cavity for intercalation of aromatic guests

Chiral porphyrin dimer with a macrocyclic cavity for intercalation of aromatic guests

Chiral diporphyrin receptor 1, which has a macrocyclic cavity to sandwich aromatic guest molecules via double π-π stacking interactions, enabled the naked-eye detection of an aromatic explosive as well as chiral discrimination in NMR.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (21), p.6090-6092
Hauptverfasser: Ema, Tadashi, Ura, Norichika, Eguchi, Katsuya, Ise, Yuhei, Sakai, Takashi
Format: Artikel
Sprache:eng
Schlagworte:
Dimerization
Dimers
Discrimination
Explosions
Explosive Agents - analysis
Holes
Intercalating Agents - chemistry
Intercalation
Macrocyclic compounds
Macrocyclic Compounds - chemistry
Magnetic Resonance Spectroscopy
Porphyrins
Porphyrins - chemistry
Receptors
Stacking
Stereoisomerism
Trinitrobenzenes - analysis
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Beschreibung
Zusammenfassung:Chiral diporphyrin receptor 1, which has a macrocyclic cavity to sandwich aromatic guest molecules via double π-π stacking interactions, enabled the naked-eye detection of an aromatic explosive as well as chiral discrimination in NMR.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc11572c