Dynamical properties of ethylene glycol and glucose studied by temperature-modulated differential scanning calorimetry and Brillouin scattering

The fragility of ethylene glycol and glucose aqueous solution systems has been investigated by temperature-modulated differential scanning calorimetry (TMDSC). The frequency and temperature dependences of complex specific heat have been observed in the vicinity of a glass-transition temperature T g...

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Veröffentlicht in:Journal of thermal analysis and calorimetry 2010, Vol.99 (1), p.45-50
Hauptverfasser: Hashimoto, Eiji, Seshimo, Yuichi, Sasanuma, Keita, Aoki, Yuichiro, Kanazawa, Hitoshi, Ike, Yuji, Kojima, Seiji
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Sprache:eng
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Zusammenfassung:The fragility of ethylene glycol and glucose aqueous solution systems has been investigated by temperature-modulated differential scanning calorimetry (TMDSC). The frequency and temperature dependences of complex specific heat have been observed in the vicinity of a glass-transition temperature T g . It is shown that the value of the fragility index m can be determined from the temperature dependence of the α-relaxation times observed by TMDSC. We have also studied the elastic properties of these aqueous solutions by micro-Brillouin scattering, and determined these relaxation times of elastic properties in the gigahertz range.
ISSN:1388-6150
1588-2926
1572-8943
DOI:10.1007/s10973-009-0543-0