Thermal behavior of 1,2,3-triazole nitrate
The thermal decomposition behaviors of 1,2,3-triazole nitrate were studied using a Calvet Microcalorimeter at four different heating rates. Its apparent activation energy and pre-exponential factor of exothermic decomposition reaction are 133.77 kJ mol −1 and 10 14.58 s −1 , respectively. The criti...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2011-06, Vol.104 (3), p.999-1004 |
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| container_title | Journal of thermal analysis and calorimetry |
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| creator | Xue, Liang Zhao, Feng-Qi Xing, Xiao-Ling Zhou, Zhi-Ming Wang, Kai Gao, Hong-Xu Yi, Jian-Hua Xu, Si-Yu Hu, Rong-Zu |
| description | The thermal decomposition behaviors of 1,2,3-triazole nitrate were studied using a Calvet Microcalorimeter at four different heating rates. Its apparent activation energy and pre-exponential factor of exothermic decomposition reaction are 133.77 kJ mol
−1
and 10
14.58
s
−1
, respectively. The critical temperature of thermal explosion is 374.97 K. The entropy of activation (Δ
S
≠
), the enthalpy of activation (Δ
H
≠
), and the free energy of activation (Δ
G
≠
) of the decomposition reaction are 23.88 J mol
−1
K
−1
, 130.62 kJ mol
−1
, and 121.55 kJ mol
−1
, respectively. The self-accelerating decomposition temperature (
T
SADT
) is 368.65 K. The specific heat capacity was determined by a Micro-DSC method and a theoretical calculation method. Specific heat capacity equation is
(283.1 K |
| doi_str_mv | 10.1007/s10973-010-1231-9 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_963839502</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A358699452</galeid><sourcerecordid>A358699452</sourcerecordid><originalsourceid>FETCH-LOGICAL-c423t-a4bc19562fc802871ee87dfc3f40bbb386854ca5fb79f4bd57d05639248d6b393</originalsourceid><addsrcrecordid>eNp9kEtLxDAUhYsoKOoPcDcbEcXqzbPJUsQXCIKPdUjSZCbSaTTpiPrrTekguJEscm_yncPhVNUBgjME0JxnBLIhNSCoESaolhvVDmJC1FhivllmUmaOGGxX-zkHAxgBl0zInerkeeHSUncz4xb6I8Q0i36GTvEpqYcU9Hfs3KwPQ9KD26u2vO6y21_fu9XL9dXz5W19_3Bzd3lxX1uKyVBraiySjGNvBWDRIOdE03pLPAVjDBFcMGo186aRnpqWNS0wTiSmouWGSLJbHU2-bym-r1we1DJk67pO9y6uspKcCCIZ4EKeTeRcd06F3scS1JbTumWwsXc-lPcLwgSXkrJRcPxHUJjBfQ5zvcpZ3T09_mXRxNoUc07Oq7cUljp9KQRqrF1NtSsY91K7GqMfrqPrbHXnk-5tyL9CTDFQkKM3nrhcvvq5S-o1rlJfWv3H_AcpQY4v</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>963839502</pqid></control><display><type>article</type><title>Thermal behavior of 1,2,3-triazole nitrate</title><source>SpringerLink Journals - AutoHoldings</source><creator>Xue, Liang ; Zhao, Feng-Qi ; Xing, Xiao-Ling ; Zhou, Zhi-Ming ; Wang, Kai ; Gao, Hong-Xu ; Yi, Jian-Hua ; Xu, Si-Yu ; Hu, Rong-Zu</creator><creatorcontrib>Xue, Liang ; Zhao, Feng-Qi ; Xing, Xiao-Ling ; Zhou, Zhi-Ming ; Wang, Kai ; Gao, Hong-Xu ; Yi, Jian-Hua ; Xu, Si-Yu ; Hu, Rong-Zu</creatorcontrib><description>The thermal decomposition behaviors of 1,2,3-triazole nitrate were studied using a Calvet Microcalorimeter at four different heating rates. Its apparent activation energy and pre-exponential factor of exothermic decomposition reaction are 133.77 kJ mol
−1
and 10
14.58
s
−1
, respectively. The critical temperature of thermal explosion is 374.97 K. The entropy of activation (Δ
S
≠
), the enthalpy of activation (Δ
H
≠
), and the free energy of activation (Δ
G
≠
) of the decomposition reaction are 23.88 J mol
−1
K
−1
, 130.62 kJ mol
−1
, and 121.55 kJ mol
−1
, respectively. The self-accelerating decomposition temperature (
T
SADT
) is 368.65 K. The specific heat capacity was determined by a Micro-DSC method and a theoretical calculation method. Specific heat capacity equation is
(283.1 K <
T
< 353.2 K). The adiabatic time-to-explosion is calculated to be a certain value between 98.82 and 100.00 s. The critical temperature of hot-spot initiation is 637.14 K, and the characteristic drop height of impact sensitivity (
H
50
) is 9.16 cm.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>EISSN: 1572-8943</identifier><identifier>DOI: 10.1007/s10973-010-1231-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Activation energy ; Adiabatic flow ; Analytical Chemistry ; Applied sciences ; Calorimetry ; Chemical industry and chemicals ; Chemistry ; Chemistry and Materials Science ; Critical temperature ; Decomposition (Chemistry) ; Decomposition reactions ; Exact sciences and technology ; Industrial chemicals ; Inorganic Chemistry ; Mathematical analysis ; Measurement Science and Instrumentation ; Nitrates ; Physical Chemistry ; Polymer Sciences ; Powders, propellants, explosives ; Specific heat ; Triazoles</subject><ispartof>Journal of thermal analysis and calorimetry, 2011-06, Vol.104 (3), p.999-1004</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2010</rights><rights>2015 INIST-CNRS</rights><rights>COPYRIGHT 2011 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c423t-a4bc19562fc802871ee87dfc3f40bbb386854ca5fb79f4bd57d05639248d6b393</citedby><cites>FETCH-LOGICAL-c423t-a4bc19562fc802871ee87dfc3f40bbb386854ca5fb79f4bd57d05639248d6b393</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-010-1231-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-010-1231-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24204092$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Xue, Liang</creatorcontrib><creatorcontrib>Zhao, Feng-Qi</creatorcontrib><creatorcontrib>Xing, Xiao-Ling</creatorcontrib><creatorcontrib>Zhou, Zhi-Ming</creatorcontrib><creatorcontrib>Wang, Kai</creatorcontrib><creatorcontrib>Gao, Hong-Xu</creatorcontrib><creatorcontrib>Yi, Jian-Hua</creatorcontrib><creatorcontrib>Xu, Si-Yu</creatorcontrib><creatorcontrib>Hu, Rong-Zu</creatorcontrib><title>Thermal behavior of 1,2,3-triazole nitrate</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>The thermal decomposition behaviors of 1,2,3-triazole nitrate were studied using a Calvet Microcalorimeter at four different heating rates. Its apparent activation energy and pre-exponential factor of exothermic decomposition reaction are 133.77 kJ mol
−1
and 10
14.58
s
−1
, respectively. The critical temperature of thermal explosion is 374.97 K. The entropy of activation (Δ
S
≠
), the enthalpy of activation (Δ
H
≠
), and the free energy of activation (Δ
G
≠
) of the decomposition reaction are 23.88 J mol
−1
K
−1
, 130.62 kJ mol
−1
, and 121.55 kJ mol
−1
, respectively. The self-accelerating decomposition temperature (
T
SADT
) is 368.65 K. The specific heat capacity was determined by a Micro-DSC method and a theoretical calculation method. Specific heat capacity equation is
(283.1 K <
T
< 353.2 K). The adiabatic time-to-explosion is calculated to be a certain value between 98.82 and 100.00 s. The critical temperature of hot-spot initiation is 637.14 K, and the characteristic drop height of impact sensitivity (
H
50
) is 9.16 cm.</description><subject>Activation energy</subject><subject>Adiabatic flow</subject><subject>Analytical Chemistry</subject><subject>Applied sciences</subject><subject>Calorimetry</subject><subject>Chemical industry and chemicals</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Critical temperature</subject><subject>Decomposition (Chemistry)</subject><subject>Decomposition reactions</subject><subject>Exact sciences and technology</subject><subject>Industrial chemicals</subject><subject>Inorganic Chemistry</subject><subject>Mathematical analysis</subject><subject>Measurement Science and Instrumentation</subject><subject>Nitrates</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Powders, propellants, explosives</subject><subject>Specific heat</subject><subject>Triazoles</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAUhYsoKOoPcDcbEcXqzbPJUsQXCIKPdUjSZCbSaTTpiPrrTekguJEscm_yncPhVNUBgjME0JxnBLIhNSCoESaolhvVDmJC1FhivllmUmaOGGxX-zkHAxgBl0zInerkeeHSUncz4xb6I8Q0i36GTvEpqYcU9Hfs3KwPQ9KD26u2vO6y21_fu9XL9dXz5W19_3Bzd3lxX1uKyVBraiySjGNvBWDRIOdE03pLPAVjDBFcMGo186aRnpqWNS0wTiSmouWGSLJbHU2-bym-r1we1DJk67pO9y6uspKcCCIZ4EKeTeRcd06F3scS1JbTumWwsXc-lPcLwgSXkrJRcPxHUJjBfQ5zvcpZ3T09_mXRxNoUc07Oq7cUljp9KQRqrF1NtSsY91K7GqMfrqPrbHXnk-5tyL9CTDFQkKM3nrhcvvq5S-o1rlJfWv3H_AcpQY4v</recordid><startdate>20110601</startdate><enddate>20110601</enddate><creator>Xue, Liang</creator><creator>Zhao, Feng-Qi</creator><creator>Xing, Xiao-Ling</creator><creator>Zhou, Zhi-Ming</creator><creator>Wang, Kai</creator><creator>Gao, Hong-Xu</creator><creator>Yi, Jian-Hua</creator><creator>Xu, Si-Yu</creator><creator>Hu, Rong-Zu</creator><general>Springer Netherlands</general><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110601</creationdate><title>Thermal behavior of 1,2,3-triazole nitrate</title><author>Xue, Liang ; Zhao, Feng-Qi ; Xing, Xiao-Ling ; Zhou, Zhi-Ming ; Wang, Kai ; Gao, Hong-Xu ; Yi, Jian-Hua ; Xu, Si-Yu ; Hu, Rong-Zu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c423t-a4bc19562fc802871ee87dfc3f40bbb386854ca5fb79f4bd57d05639248d6b393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Activation energy</topic><topic>Adiabatic flow</topic><topic>Analytical Chemistry</topic><topic>Applied sciences</topic><topic>Calorimetry</topic><topic>Chemical industry and chemicals</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Critical temperature</topic><topic>Decomposition (Chemistry)</topic><topic>Decomposition reactions</topic><topic>Exact sciences and technology</topic><topic>Industrial chemicals</topic><topic>Inorganic Chemistry</topic><topic>Mathematical analysis</topic><topic>Measurement Science and Instrumentation</topic><topic>Nitrates</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Powders, propellants, explosives</topic><topic>Specific heat</topic><topic>Triazoles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xue, Liang</creatorcontrib><creatorcontrib>Zhao, Feng-Qi</creatorcontrib><creatorcontrib>Xing, Xiao-Ling</creatorcontrib><creatorcontrib>Zhou, Zhi-Ming</creatorcontrib><creatorcontrib>Wang, Kai</creatorcontrib><creatorcontrib>Gao, Hong-Xu</creatorcontrib><creatorcontrib>Yi, Jian-Hua</creatorcontrib><creatorcontrib>Xu, Si-Yu</creatorcontrib><creatorcontrib>Hu, Rong-Zu</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xue, Liang</au><au>Zhao, Feng-Qi</au><au>Xing, Xiao-Ling</au><au>Zhou, Zhi-Ming</au><au>Wang, Kai</au><au>Gao, Hong-Xu</au><au>Yi, Jian-Hua</au><au>Xu, Si-Yu</au><au>Hu, Rong-Zu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal behavior of 1,2,3-triazole nitrate</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2011-06-01</date><risdate>2011</risdate><volume>104</volume><issue>3</issue><spage>999</spage><epage>1004</epage><pages>999-1004</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><eissn>1572-8943</eissn><abstract>The thermal decomposition behaviors of 1,2,3-triazole nitrate were studied using a Calvet Microcalorimeter at four different heating rates. Its apparent activation energy and pre-exponential factor of exothermic decomposition reaction are 133.77 kJ mol
−1
and 10
14.58
s
−1
, respectively. The critical temperature of thermal explosion is 374.97 K. The entropy of activation (Δ
S
≠
), the enthalpy of activation (Δ
H
≠
), and the free energy of activation (Δ
G
≠
) of the decomposition reaction are 23.88 J mol
−1
K
−1
, 130.62 kJ mol
−1
, and 121.55 kJ mol
−1
, respectively. The self-accelerating decomposition temperature (
T
SADT
) is 368.65 K. The specific heat capacity was determined by a Micro-DSC method and a theoretical calculation method. Specific heat capacity equation is
(283.1 K <
T
< 353.2 K). The adiabatic time-to-explosion is calculated to be a certain value between 98.82 and 100.00 s. The critical temperature of hot-spot initiation is 637.14 K, and the characteristic drop height of impact sensitivity (
H
50
) is 9.16 cm.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-010-1231-9</doi><tpages>6</tpages></addata></record> |
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| subjects | Activation energy Adiabatic flow Analytical Chemistry Applied sciences Calorimetry Chemical industry and chemicals Chemistry Chemistry and Materials Science Critical temperature Decomposition (Chemistry) Decomposition reactions Exact sciences and technology Industrial chemicals Inorganic Chemistry Mathematical analysis Measurement Science and Instrumentation Nitrates Physical Chemistry Polymer Sciences Powders, propellants, explosives Specific heat Triazoles |
| title | Thermal behavior of 1,2,3-triazole nitrate |
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