NC Coupling of NO Ligands with β-Carbon Atoms in Aliphatic Tertiary Amines on Nitrosylruthenium Complexes Accompanying Oxidative Dehydrogenation of Amines and CH Activation

Doctor NO: Unprecedented β‐carbon nitrosation of aliphatic tertiary amines on nitrosylruthenium complexes was revealed, where aerobic oxidative dehydrogenation of amines, CH bond activation, NC coupling, and enamine hydrolysis were involved.

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Veröffentlicht in:Chemistry, an Asian journal an Asian journal, 2012-04, Vol.7 (4), p.664-666
Hauptverfasser: Asayama, Taiki, Arikawa, Yasuhiro, Murabe, Takerou, Agari, Shoko, Umakoshi, Keisuke, Onishi, Masayoshi
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Sprache:eng
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Zusammenfassung:Doctor NO: Unprecedented β‐carbon nitrosation of aliphatic tertiary amines on nitrosylruthenium complexes was revealed, where aerobic oxidative dehydrogenation of amines, CH bond activation, NC coupling, and enamine hydrolysis were involved.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201100816