Diastereoselective generation of triple-stranded helicates induced by gem-dimethyl groups on a linker

Diastereoselective generation of triple-stranded helicates induced by gem-dimethyl groups on a linker

The diastereoselectivity of the self-assembly of bis(dipyrromethene) ligands with trivalent metals was improved by introducing gem-dimethyl groups to the linker.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-04, Vol.41 (16), p.4751-4753
Hauptverfasser: Zhang, Zhan, Chen, Yakun, Dolphin, David
Format: Artikel
Sprache:eng
Schlagworte:
Ligands
Self assembly
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Zusammenfassung:The diastereoselectivity of the self-assembly of bis(dipyrromethene) ligands with trivalent metals was improved by introducing gem-dimethyl groups to the linker.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt12316a