Indium(III) catalysed substrate selective hydrothiolation of terminal alkynes

In(OTf)(3) is reported as the first catalyst having the ability to selectively catalyse both Markovnikov and anti-Markovnikov hydrothiolation of terminal alkynes under identical reaction conditions depending upon the nature of the thiol employed.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2012-04, Vol.48 (33), p.4014-4016
Hauptverfasser:	Sarma, Rupam, Rajesh, Nimmakuri, Prajapati, Dipak
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Alkynes - chemistry Catalysis Catalysts Indium - chemistry Substrate Specificity Sulfhydryl Compounds - chemistry Terminals Thiols
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Beschreibung
Zusammenfassung:	In(OTf)(3) is reported as the first catalyst having the ability to selectively catalyse both Markovnikov and anti-Markovnikov hydrothiolation of terminal alkynes under identical reaction conditions depending upon the nature of the thiol employed.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c2cc30350g