Rapid determination of the optical and redox properties of a metal-organic framework via in situ solid state spectroelectrochemistry

Rapid determination of the optical and redox properties of a metal-organic framework via in situ solid state spectroelectrochemistry

The optical properties of [Zn(2)(NDC)(2)(DPNI)](0/-/2-) (NDC = 2,7-naphthalene dicarboxylate, DPNI = N,N'-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide), a redox-active metal-organic framework, have been examined using a simple and robust in situ solid state UV-Vis-NIR spectroelectrochem...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (33), p.3945-3947
Hauptverfasser: Usov, Pavel M, Fabian, Cesimiro, D'Alessandro, Deanna M
Format: Artikel
Sprache:eng
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Zusammenfassung:The optical properties of [Zn(2)(NDC)(2)(DPNI)](0/-/2-) (NDC = 2,7-naphthalene dicarboxylate, DPNI = N,N'-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide), a redox-active metal-organic framework, have been examined using a simple and robust in situ solid state UV-Vis-NIR spectroelectrochemical technique.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc30568b