Self-Assembly of M24L48 Polyhedra Based on Empirical Prediction

Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M12L24 or M24L48). This molecular‐level emergent behavior was predicted from the empirical threshold of the ligand be...

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Veröffentlicht in:	Angewandte Chemie International Edition 2012-03, Vol.51 (13), p.3161-3163
Hauptverfasser:	Bunzen, Jens, Iwasa, Junji, Bonakdarzadeh, Pia, Numata, Eri, Rissanen, Kari, Sato, Sota, Fujita, Makoto
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Sprache:	eng
Schlagworte:	palladium pyrroles self-assembly spherical structures
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description	Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M12L24 or M24L48). This molecular‐level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M12L24/M24L48 switchover.
doi_str_mv	10.1002/anie.201108731
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subjects	palladium pyrroles self-assembly spherical structures
title	Self-Assembly of M24L48 Polyhedra Based on Empirical Prediction
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