Self-Assembly of M24L48 Polyhedra Based on Empirical Prediction

Self-Assembly of M24L48 Polyhedra Based on Empirical Prediction

Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M12L24 or M24L48). This molecular‐level emergent behavior was predicted from the empirical threshold of the ligand be...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-03, Vol.51 (13), p.3161-3163
Hauptverfasser: Bunzen, Jens, Iwasa, Junji, Bonakdarzadeh, Pia, Numata, Eri, Rissanen, Kari, Sato, Sota, Fujita, Makoto
Format: Artikel
Sprache:eng
Schlagworte:
palladium
pyrroles
self-assembly
spherical structures
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Zusammenfassung:Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M12L24 or M24L48). This molecular‐level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M12L24/M24L48 switchover.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201108731