Reactivity of scandium terminal imido complexes towards metal halides

Reactivity of scandium terminal imido complexes towards metal halides

Reactions of scandium terminal imido complexes with CuI and [M(COD)Cl](2) (M = Rh, Ir) show two interesting reaction patterns, and the formed heterobimetallic complexes have intriguing structural features and show promising catalytic properties.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (28), p.3403-3405
Hauptverfasser: Lu, Erli, Zhou, Qinghai, Li, Yuxue, Chu, Jiaxiang, Chen, Yaofeng, Leng, Xuebing, Sun, Jie
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalysts
Iridium
Metal halides
Scandium
Terminals
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Zusammenfassung:Reactions of scandium terminal imido complexes with CuI and [M(COD)Cl](2) (M = Rh, Ir) show two interesting reaction patterns, and the formed heterobimetallic complexes have intriguing structural features and show promising catalytic properties.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc30220a