The Nature of Trapping Centers in Amorphous Biphenyl-Containing Polymer

Study of optical properties of methyl methacrylate and 4-vinylbiphenyl copolymers in a rigid amorphous polymer allowed establishing the non-excimer nature of energy traps in a polymer chain. These traps are probably related to possibility of collective states formed by macromolecule’s chromophore gr...

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Veröffentlicht in:Journal of fluorescence 2011-07, Vol.21 (4), p.1521-1524
Hauptverfasser: Adadurov, Alexanser F., Bedrik, Alexandra I., Yelyseev, Dmitriy A., Velmozhnaya, Elena C., Zhmurin, Piotr N., Lebedev, Valentin N., Titskaya, Valentina D.
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Sprache:eng
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Zusammenfassung:Study of optical properties of methyl methacrylate and 4-vinylbiphenyl copolymers in a rigid amorphous polymer allowed establishing the non-excimer nature of energy traps in a polymer chain. These traps are probably related to possibility of collective states formed by macromolecule’s chromophore groups. The shortening of the trap states decay time in 4-vinylbiphenyl homopolymer comparing to copolymer is observed.
ISSN:1053-0509
1573-4994
DOI:10.1007/s10895-011-0839-x