Growth of homogeneous polycrystalline Si1-xGex and Mg2Si1-xGex for thermoelectric application

Homogeneous polycrystalline Si1-xGex were grown using a Si(seed)/Ge/Si(feed) sandwich structure under the low temperature gradient less than 0.4 degree C/mm. It was found that the composition of the Si1-xGex was controlled by the growth temperature. The homogeneous Mg2Si1-xGex was synthesized by hea...

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Veröffentlicht in:Thin solid films 2011-10, Vol.519 (24), p.8532-8537
Hauptverfasser: HAYAKAWA, Yasuhiro, ARIVANANDHAN, Mukannan, BHATTACHARYA, Shovit, ASWAL, Dinesh Kumar, BABU, Sridharan Moorthy, INATOMI, Yuko, TATSUOKA, Hirokazu, SAITO, Yosuke, KOYAMA, Tadanobu, MOMOSE, Yoshimi, IKEDA, Hiroya, TANAKA, Akira, WEN, Cuilian, KUBOTA, Yoshihiro, NAKAMURA, Tamotsu
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Sprache:eng
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Zusammenfassung:Homogeneous polycrystalline Si1-xGex were grown using a Si(seed)/Ge/Si(feed) sandwich structure under the low temperature gradient less than 0.4 degree C/mm. It was found that the composition of the Si1-xGex was controlled by the growth temperature. The homogeneous Mg2Si1-xGex was synthesized by heat treatment of the homogeneous Si1-xGex powders under Mg vapor. The Mg2Si1-xGex sample with the relative density of 95% was synthesized by spark plasma sintering technique. The resistivity and the Seebeck coefficient of the Si, Ge, Si1-xGex and Mg2Si1-xGex samples were evaluated as a function of temperature. It indicated that Seebeck coefficients of the Si1-xGex and Mg2Si1-xGex samples were higher than those of Si and Ge. Moreover, the Seebeck coefficient of Mg2Si0.7Ge0.3 sample was higher than that of Mg2Si0.5Ge0.5 and Si0.5Ge0.5 samples.
ISSN:0040-6090
1879-2731
DOI:10.1016/j.tsf.2011.05.033