SiC fibre by chemical vapour deposition on tungsten filament

A CVD system for the production of continuous SiC fibre was set up. The process of SiC coating on 19 mu m diameter tungsten substrate was studied. Methyl trichloro silane (CH sub(3)SiCl sub(3)) and hydrogen reactants were used. Effect of substrate temperature (1300-1500 degree C) and concentration o...

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Veröffentlicht in:Bulletin of materials science 2001-06, Vol.24 (3), p.273-279
Hauptverfasser: Krishnarao, R V, Subrahmanyam, J, Subbarao, S
Format: Artikel
Sprache:eng
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Zusammenfassung:A CVD system for the production of continuous SiC fibre was set up. The process of SiC coating on 19 mu m diameter tungsten substrate was studied. Methyl trichloro silane (CH sub(3)SiCl sub(3)) and hydrogen reactants were used. Effect of substrate temperature (1300-1500 degree C) and concentration of reactants on the formation of SiC coating were studied. SiC coatings of negligible thickness were formed at very low flow rates of hydrogen (5 x 10 super(-5) m super(3)/min) and CH sub(3)SiCl sub(3) (1.0 x 10 super(-4) m super(3)/min of Ar). Uneven coatings and brittle fibres were formed at very high concentrations of CH sub(3)SiCl sub(3) (6 x 10 super(-4) m super(3)/min of Ar). The flow rates of CH sub(3)SiCl sub(3) and hydrogen were adjusted to get SiC fibre with smooth surface. The structure and morphology of SiC fibres were evaluated.
ISSN:0250-4707
0973-7669
DOI:10.1007/BF02704921