Ruthenium-catalyzed annulation of alkynes with amides via formyl translocation

The first example of Ru-catalyzed intramolecular annulation of alkynes with amides via formyl translocation has been developed, which provides an efficient approach for the synthesis of 1H-indole-3-carbaldehydes.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2012-03, Vol.48 (26), p.3197-3199
Hauptverfasser:	Wu, Cui-Yan, Hu, Ming, Liu, Yu, Song, Ren-Jie, Lei, Yong, Tang, Bo-Xiao, Li, Rong-Jiang, Li, Jin-Heng
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemical synthesis Aldehydes - chemistry Alkynes - chemistry Amides - chemistry Catalysis Cyclization Molecular Structure Organometallic Compounds - chemistry Ruthenium - chemistry Stereoisomerism
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Beschreibung
Zusammenfassung:	The first example of Ru-catalyzed intramolecular annulation of alkynes with amides via formyl translocation has been developed, which provides an efficient approach for the synthesis of 1H-indole-3-carbaldehydes.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c2cc17887g