A Halide-Induced Copper(I) Disulfide/Copper(II) Thiolate Interconversion

A Halide-Induced Copper(I) Disulfide/Copper(II) Thiolate Interconversion

One to two and back again: A disulfide–thiolate interconversion process in a dinuclear copper complex is induced by chloride ions (see scheme). Within this compound, the coordinating copper atoms serve either as electron source or as electron sink and thus oscillate between the oxidation states +I a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2012-02, Vol.51 (7), p.1714-1718
Hauptverfasser: Neuba, Adam, Haase, Roxana, Meyer-Klaucke, Wolfram, Flörke, Ulrich, Henkel, Gerald
Format: Artikel
Sprache:eng
Schlagworte:
bioinorganic chemistry
Chloride ions
Chlorides - chemistry
Copper
Copper - chemistry
COPPER COMPOUNDS
copper sulfur complexes
Crystallography, X-Ray
disulfide-thiolate interconversion
Disulfides
Disulfides - chemistry
Electron sources
HALIDES
Models, Molecular
Molecular Structure
Organometallic Compounds - chemistry
Oxidation
structure elucidation
Sulfhydryl Compounds - chemistry
SULFIDES
VALENCE
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:One to two and back again: A disulfide–thiolate interconversion process in a dinuclear copper complex is induced by chloride ions (see scheme). Within this compound, the coordinating copper atoms serve either as electron source or as electron sink and thus oscillate between the oxidation states +I and +II.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201102714