Anodic dissolution of Pb-Sb alloys in an equimolar mixture of potassium and lead chlorides

The effect of temperature and antimony concentration on the anodic dissolution of Pb-Sb alloys in an equimolar KCl-PbCl 2 melt is investigated. It is shown that, up to the specific values of the current densities, the main process is lead dissolution, which starts at near-equilibrium potentials. The...

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Veröffentlicht in:Russian journal of non-ferrous metals 2008-08, Vol.49 (4), p.225-230
Hauptverfasser: Zaikov, Yu. P., Arkhipov, P. A., Plekhanov, K. A., Ashikhin, V. V., Khalimullina, Yu. R., Khramov, A. P.
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Sprache:eng
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Zusammenfassung:The effect of temperature and antimony concentration on the anodic dissolution of Pb-Sb alloys in an equimolar KCl-PbCl 2 melt is investigated. It is shown that, up to the specific values of the current densities, the main process is lead dissolution, which starts at near-equilibrium potentials. The theoretical anode polarization curve for the dissolution of Pb-Sb alloys is calculated. It is established that the limiting stage is the mass transfer from the alloy side.
ISSN:1067-8212
1934-970X
DOI:10.3103/S1067821208040020