Properties of Nafion membranes under PEM water electrolysis conditions

A comprehensive overview of the properties of Nafion membranes under electrolysis conditions is presented here to help evaluate and design high-pressure operating proton exchange membrane (PEM) electrolyzers. First, the properties of Nafion membranes are reviewed and summarized based on literature d...

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Veröffentlicht in:International journal of hydrogen energy 2011-08, Vol.36 (17), p.10527-10540
Hauptverfasser: Ito, Hiroshi, Maeda, Tetsuhiko, Nakano, Akihiro, Takenaka, Hiroyasu
Format: Artikel
Sprache:eng
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Zusammenfassung:A comprehensive overview of the properties of Nafion membranes under electrolysis conditions is presented here to help evaluate and design high-pressure operating proton exchange membrane (PEM) electrolyzers. First, the properties of Nafion membranes are reviewed and summarized based on literature data for PEM electrolysis conditions. Second, the solubility and diffusivity of H 2 and O 2 in liquid water and the PEM are reviewed based on literature data. Finally, the relationship between current density and the impurity of gases is reviewed and discussed. ► The properties of Nafion membranes under PEM electrolysis conditions are reviewed. ► The solubility and diffusivity of H 2 and O 2 in liquid water and Nafion are reviewed. ► The relationship between current density and the impurity of gases is reviewed and discussed.
ISSN:0360-3199
1879-3487
DOI:10.1016/j.ijhydene.2011.05.127