Fibre optic ATR-IR spectroscopy at cryogenic temperatures: in-line reaction monitoring on organolithium compounds

Fibre optic ATR-IR spectroscopy at cryogenic temperatures: in-line reaction monitoring on organolithium compounds

A reliable methodology, utilising an ATR-IR fibre probe, for in-line monitoring of low temperature reactions is presented. The application of this convenient set-up enables a fast and safe exploration of highly reactive substrates. Hence, in situ monitoring of lithiation reactions is realised and th...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (18), p.2451-2453
Hauptverfasser: Lumpi, Daniel, Wagner, Christoph, Schöpf, Matthias, Horkel, Ernst, Ramer, Georg, Lendl, Bernhard, Fröhlich, Johannes
Format: Artikel
Sprache:eng
Schlagworte:
Cryogenic temperature
Exploration
Fiber optics
Fibre
Infrared spectroscopy
Monitoring
Optical fibers
Organolithium compounds
Spectroscopy
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Beschreibung
Zusammenfassung:A reliable methodology, utilising an ATR-IR fibre probe, for in-line monitoring of low temperature reactions is presented. The application of this convenient set-up enables a fast and safe exploration of highly reactive substrates. Hence, in situ monitoring of lithiation reactions is realised and the potential to investigate sensitive intermediates is being demonstrated.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc16016a