A porous metal-organic framework (MOF) with unusual 2D→3D polycatenation based on honeycomb layers

A porous metal-organic framework (MOF) with unusual 2D→3D polycatenation based on honeycomb layers

A novel mixed-ligand 3D metal-organic framework (MOF), {Zn(2)(TMTA)(bipy)(0.5)(H(2)O)(2)·NO(3)·2DMF·H(2)O}(n) (1) (H(3)TMTA = 4,4',4''-(2,4,6-trimethylbenzene-1,3,5-triyl)tribenzoic acid, bipy = 4,4'-bipyridine, DMF = dimethylformamide), was constructed based on bipy-pillared hon...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-02, Vol.41 (7), p.1928-1930
Hauptverfasser: Zhao, Xiaoliang, Dou, Jianmin, Sun, Di, Cui, Peipei, Sun, Daofeng, Wu, Qingyin
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel mixed-ligand 3D metal-organic framework (MOF), {Zn(2)(TMTA)(bipy)(0.5)(H(2)O)(2)·NO(3)·2DMF·H(2)O}(n) (1) (H(3)TMTA = 4,4',4''-(2,4,6-trimethylbenzene-1,3,5-triyl)tribenzoic acid, bipy = 4,4'-bipyridine, DMF = dimethylformamide), was constructed based on bipy-pillared honeycomb bilayers and showed the unusual 2D→3D polycatenation of bilayers.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt11898j