Activity and stability of BaKCo/CeO sub(2 catalysts for diesel soot oxidation)

The activity and stability of Ba,K,Co/CeO sub(2 catalyst in the diesel soot oxidation reaction are studied. Different modes of preparation are analyzed, varying both the cobalt precursor and its order of impregnation. In order to study the stability in a diesel exhaust atmosphere, the catalysts were pretreated in streams of CO) sub(2), H sub(2O, NO and SO) sub(2). The fresh and the treated catalysts were characterized by FTIR and XRD techniques. The catalytic activity was measured by TPO of soot-catalyst mixtures. The tight contact was used to analyze the intrinsic activity. It was found that the activity was higher for the catalysts prepared using Co(NO sub(3)) sub(2) compared with the catalysts prepared using Co(AcO) sub(2. This is because in the former, KNO) sub(3) is present on the catalyst, being this compound very active for this reaction. The thermal stability is lower for the catalyst prepared with Co(NO sub(3)) sub(2). This catalyst displays a higher K lost when treated at high temperature. When K is present as K sub(2CO) sub(3), as is the case of the catalysts prepared with Co(AcO) sub(2, the thermal stability is higher since K) sub(2)CO sub(3 is less volatile than KNO) sub(3). All the catalysts are stable in the presence of mixtures of (CO sub(2 + H) sub(2)O + NO + O sub(2) having a composition similar to a real diesel exhaust. Under these conditions, the K mantains its original chemical state, either carbonate or nitrate, depending on the precursor used in the catalyst preparation. In presence of SO) sub(2), all the catalysts deactivate due to K sub(2SO) sub(4) formation, which is not active for soot combustion. However, the sensitivity to SO sub(2 depends on the precursors used to prepare the catalyst. The Ba,K,Co/CeO) sub(2) catalyst prepared impregnating Co(NO sub(3)) sub(2) on the Ba,K/CeO sub(2 catalyst has a higher resistance to the deactivation by SO) sub(2), since the following reaction occurs: Ba sub(2(NO) sub(3))+K sub(2SO) sub(4)right arrowBaSO sub(4+KNO) sub(3), which implies that active KNO sub(3 will dissapear slower from the catalytic surface, thus maintaining the activity. TPO experiments of the catalyst in loose contact with soot were also carried out. The Ba,K,Co/CeO) sub(2) catalyst prepared impregnating Co(NO sub(3)) sub(2) on the Ba,K/CeO sub(2 catalyst showed the higher activity in loose contact mode.)