A novel structure of ceramics electrolyte for future lithium battery
► We propose a novel type 3 dimensionally battery with porous layer in honeycomb hole. ► The porous membrane was pushed into honeycomb hole and calcined. ► After impregnation of LiMn 2O 4, the cell showed clear charge/discharge behavior. ► It was proven that this structure can be applied to the all-...
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| Veröffentlicht in: | Journal of power sources 2011-11, Vol.196 (22), p.9815-9819 |
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| container_issue | 22 |
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| container_title | Journal of power sources |
| container_volume | 196 |
| creator | Kotobuki, Masashi Suzuki, Yuji Kanamura, Kiyoshi Sato, Yosuke Yamamoto, Kazuhiro Yoshida, Toshihiro |
| description | ► We propose a novel type 3 dimensionally battery with porous layer in honeycomb hole. ► The porous membrane was pushed into honeycomb hole and calcined. ► After impregnation of LiMn
2O
4, the cell showed clear charge/discharge behavior. ► It was proven that this structure can be applied to the all-solid-state battery. ► This structure would be one of the promising structures for large scale battery.
In order to fabricate large scale all-solid-state Li battery, we suggested a novel structure of solid electrolyte, which is composed of porous electrolyte supported by honeycomb-type electrolyte. A possibility of fabrication of the honeycomb-supported porous electrolyte and a compatibility of this structure with all-solid-state battery were examined using LLT (Li
0.35La
0.55TiO
3) solid electrolyte which is one of the anticipated solid electrolytes due to its high Li ion conductivity. A porous layer membrane with 3 dimensionally ordered (3DOM) macroporous structure was prepared by a colloidal crystal templating method. The porous honeycomb was fabricated by pushing the membrane into holes of honycomb using a needle followed by calcination. The 3DOM membrane and honeycmb electrolyte were sintered well each other. After filling the 3DOM pores with LiMn
2O
4 cathode material, the compatibility of this novel porous honeycomb electrolyte with all-solid-state battery was examined. The LiMn
2O
4/porous honeycomb cell clearly demonstrated charge and discharge behaviors, indicating the porous honeycomb structure can be applied to the all-solid-state battery. The discharge capacity was 71
mA
h
g
−1 (1.3
mA
h
cm
−2) at 30
°C. |
| doi_str_mv | 10.1016/j.jpowsour.2011.07.005 |
| format | Article |
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2O
4, the cell showed clear charge/discharge behavior. ► It was proven that this structure can be applied to the all-solid-state battery. ► This structure would be one of the promising structures for large scale battery.
In order to fabricate large scale all-solid-state Li battery, we suggested a novel structure of solid electrolyte, which is composed of porous electrolyte supported by honeycomb-type electrolyte. A possibility of fabrication of the honeycomb-supported porous electrolyte and a compatibility of this structure with all-solid-state battery were examined using LLT (Li
0.35La
0.55TiO
3) solid electrolyte which is one of the anticipated solid electrolytes due to its high Li ion conductivity. A porous layer membrane with 3 dimensionally ordered (3DOM) macroporous structure was prepared by a colloidal crystal templating method. The porous honeycomb was fabricated by pushing the membrane into holes of honycomb using a needle followed by calcination. The 3DOM membrane and honeycmb electrolyte were sintered well each other. After filling the 3DOM pores with LiMn
2O
4 cathode material, the compatibility of this novel porous honeycomb electrolyte with all-solid-state battery was examined. The LiMn
2O
4/porous honeycomb cell clearly demonstrated charge and discharge behaviors, indicating the porous honeycomb structure can be applied to the all-solid-state battery. The discharge capacity was 71
mA
h
g
−1 (1.3
mA
h
cm
−2) at 30
°C.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2011.07.005</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>3-D battery ; All-solid-state Li ion battery ; Applied sciences ; Battery ; Direct energy conversion and energy accumulation ; Discharge ; Electric batteries ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrolytes ; Exact sciences and technology ; Honeycomb ; Honeycomb construction ; Membranes ; Solid electrolyte ; Solid electrolytes ; Sol–gel method</subject><ispartof>Journal of power sources, 2011-11, Vol.196 (22), p.9815-9819</ispartof><rights>2011 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c514t-cb1c4a563f3055b05509c6a2c38be34a97bfb48f0a2e0b9e4a9d497a2564de9b3</citedby><cites>FETCH-LOGICAL-c514t-cb1c4a563f3055b05509c6a2c38be34a97bfb48f0a2e0b9e4a9d497a2564de9b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jpowsour.2011.07.005$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24566159$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kotobuki, Masashi</creatorcontrib><creatorcontrib>Suzuki, Yuji</creatorcontrib><creatorcontrib>Kanamura, Kiyoshi</creatorcontrib><creatorcontrib>Sato, Yosuke</creatorcontrib><creatorcontrib>Yamamoto, Kazuhiro</creatorcontrib><creatorcontrib>Yoshida, Toshihiro</creatorcontrib><title>A novel structure of ceramics electrolyte for future lithium battery</title><title>Journal of power sources</title><description>► We propose a novel type 3 dimensionally battery with porous layer in honeycomb hole. ► The porous membrane was pushed into honeycomb hole and calcined. ► After impregnation of LiMn
2O
4, the cell showed clear charge/discharge behavior. ► It was proven that this structure can be applied to the all-solid-state battery. ► This structure would be one of the promising structures for large scale battery.
In order to fabricate large scale all-solid-state Li battery, we suggested a novel structure of solid electrolyte, which is composed of porous electrolyte supported by honeycomb-type electrolyte. A possibility of fabrication of the honeycomb-supported porous electrolyte and a compatibility of this structure with all-solid-state battery were examined using LLT (Li
0.35La
0.55TiO
3) solid electrolyte which is one of the anticipated solid electrolytes due to its high Li ion conductivity. A porous layer membrane with 3 dimensionally ordered (3DOM) macroporous structure was prepared by a colloidal crystal templating method. The porous honeycomb was fabricated by pushing the membrane into holes of honycomb using a needle followed by calcination. The 3DOM membrane and honeycmb electrolyte were sintered well each other. After filling the 3DOM pores with LiMn
2O
4 cathode material, the compatibility of this novel porous honeycomb electrolyte with all-solid-state battery was examined. The LiMn
2O
4/porous honeycomb cell clearly demonstrated charge and discharge behaviors, indicating the porous honeycomb structure can be applied to the all-solid-state battery. The discharge capacity was 71
mA
h
g
−1 (1.3
mA
h
cm
−2) at 30
°C.</description><subject>3-D battery</subject><subject>All-solid-state Li ion battery</subject><subject>Applied sciences</subject><subject>Battery</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Discharge</subject><subject>Electric batteries</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrolytes</subject><subject>Exact sciences and technology</subject><subject>Honeycomb</subject><subject>Honeycomb construction</subject><subject>Membranes</subject><subject>Solid electrolyte</subject><subject>Solid electrolytes</subject><subject>Sol–gel method</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqF0M9LwzAUwPEgCs7pvyC9iF5aX9qmaW8Of8PAi55Dmr5gSrfMJJ3svzdz06MeQiB8Xh58CTmnkFGg1XWf9Sv76e3oshwozYBnAOyATGjNizTnjB2SCRS8TjlnxTE58b4HiJLDhNzNkqVd45D44EYVRoeJ1YlCJxdG-QQHVMHZYRMw0dYlevwmgwnvZlwkrQwB3eaUHGk5eDzb31Py9nD_evuUzl8en29n81QxWoZUtVSVklWFLoCxNh5oVCVzVdQtFqVseKvbstYgc4S2wfjSlQ2XOavKDpu2mJLL3b8rZz9G9EEsjFc4DHKJdvSioTWUnPI8yqs_JeU8OkppHWm1o8pZ7x1qsXJmId1GUBDbwKIXP4HFNrAALmLgOHix3yG9koN2cqmM_53OS1ZVlDXR3ewcxjRrg054ZXCpsDMu1hWdNf-t-gImW5V2</recordid><startdate>20111115</startdate><enddate>20111115</enddate><creator>Kotobuki, Masashi</creator><creator>Suzuki, Yuji</creator><creator>Kanamura, Kiyoshi</creator><creator>Sato, Yosuke</creator><creator>Yamamoto, Kazuhiro</creator><creator>Yoshida, Toshihiro</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SP</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>L7M</scope><scope>7ST</scope><scope>SOI</scope></search><sort><creationdate>20111115</creationdate><title>A novel structure of ceramics electrolyte for future lithium battery</title><author>Kotobuki, Masashi ; Suzuki, Yuji ; Kanamura, Kiyoshi ; Sato, Yosuke ; Yamamoto, Kazuhiro ; Yoshida, Toshihiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c514t-cb1c4a563f3055b05509c6a2c38be34a97bfb48f0a2e0b9e4a9d497a2564de9b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>3-D battery</topic><topic>All-solid-state Li ion battery</topic><topic>Applied sciences</topic><topic>Battery</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Discharge</topic><topic>Electric batteries</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrolytes</topic><topic>Exact sciences and technology</topic><topic>Honeycomb</topic><topic>Honeycomb construction</topic><topic>Membranes</topic><topic>Solid electrolyte</topic><topic>Solid electrolytes</topic><topic>Sol–gel method</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kotobuki, Masashi</creatorcontrib><creatorcontrib>Suzuki, Yuji</creatorcontrib><creatorcontrib>Kanamura, Kiyoshi</creatorcontrib><creatorcontrib>Sato, Yosuke</creatorcontrib><creatorcontrib>Yamamoto, Kazuhiro</creatorcontrib><creatorcontrib>Yoshida, Toshihiro</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kotobuki, Masashi</au><au>Suzuki, Yuji</au><au>Kanamura, Kiyoshi</au><au>Sato, Yosuke</au><au>Yamamoto, Kazuhiro</au><au>Yoshida, Toshihiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel structure of ceramics electrolyte for future lithium battery</atitle><jtitle>Journal of power sources</jtitle><date>2011-11-15</date><risdate>2011</risdate><volume>196</volume><issue>22</issue><spage>9815</spage><epage>9819</epage><pages>9815-9819</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>► We propose a novel type 3 dimensionally battery with porous layer in honeycomb hole. ► The porous membrane was pushed into honeycomb hole and calcined. ► After impregnation of LiMn
2O
4, the cell showed clear charge/discharge behavior. ► It was proven that this structure can be applied to the all-solid-state battery. ► This structure would be one of the promising structures for large scale battery.
In order to fabricate large scale all-solid-state Li battery, we suggested a novel structure of solid electrolyte, which is composed of porous electrolyte supported by honeycomb-type electrolyte. A possibility of fabrication of the honeycomb-supported porous electrolyte and a compatibility of this structure with all-solid-state battery were examined using LLT (Li
0.35La
0.55TiO
3) solid electrolyte which is one of the anticipated solid electrolytes due to its high Li ion conductivity. A porous layer membrane with 3 dimensionally ordered (3DOM) macroporous structure was prepared by a colloidal crystal templating method. The porous honeycomb was fabricated by pushing the membrane into holes of honycomb using a needle followed by calcination. The 3DOM membrane and honeycmb electrolyte were sintered well each other. After filling the 3DOM pores with LiMn
2O
4 cathode material, the compatibility of this novel porous honeycomb electrolyte with all-solid-state battery was examined. The LiMn
2O
4/porous honeycomb cell clearly demonstrated charge and discharge behaviors, indicating the porous honeycomb structure can be applied to the all-solid-state battery. The discharge capacity was 71
mA
h
g
−1 (1.3
mA
h
cm
−2) at 30
°C.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2011.07.005</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
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| language | eng |
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| source | Elsevier ScienceDirect |
| subjects | 3-D battery All-solid-state Li ion battery Applied sciences Battery Direct energy conversion and energy accumulation Discharge Electric batteries Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrolytes Exact sciences and technology Honeycomb Honeycomb construction Membranes Solid electrolyte Solid electrolytes Sol–gel method |
| title | A novel structure of ceramics electrolyte for future lithium battery |
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