A novel structure of ceramics electrolyte for future lithium battery

► We propose a novel type 3 dimensionally battery with porous layer in honeycomb hole. ► The porous membrane was pushed into honeycomb hole and calcined. ► After impregnation of LiMn 2O 4, the cell showed clear charge/discharge behavior. ► It was proven that this structure can be applied to the all-solid-state battery. ► This structure would be one of the promising structures for large scale battery. In order to fabricate large scale all-solid-state Li battery, we suggested a novel structure of solid electrolyte, which is composed of porous electrolyte supported by honeycomb-type electrolyte. A possibility of fabrication of the honeycomb-supported porous electrolyte and a compatibility of this structure with all-solid-state battery were examined using LLT (Li 0.35La 0.55TiO 3) solid electrolyte which is one of the anticipated solid electrolytes due to its high Li ion conductivity. A porous layer membrane with 3 dimensionally ordered (3DOM) macroporous structure was prepared by a colloidal crystal templating method. The porous honeycomb was fabricated by pushing the membrane into holes of honycomb using a needle followed by calcination. The 3DOM membrane and honeycmb electrolyte were sintered well each other. After filling the 3DOM pores with LiMn 2O 4 cathode material, the compatibility of this novel porous honeycomb electrolyte with all-solid-state battery was examined. The LiMn 2O 4/porous honeycomb cell clearly demonstrated charge and discharge behaviors, indicating the porous honeycomb structure can be applied to the all-solid-state battery. The discharge capacity was 71 mA h g −1 (1.3 mA h cm −2) at 30 °C.